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HomeMy WebLinkAbout8.a. U.S.P.C.I. Interim Use Permit - Set Public Hearing. � �. a � . . � . Cit�r of Rosemount Executive Summary for Action City Conac�l Meetiz�g Date: June 1, 1993 Ageuda Item: IUP Amendment ta a11aw Coal. Agenda Sectiom; Ash Disposal at MICF - - Set PUBLIC HEAFtSNG Public Hear,ing Prepared 8y: Lisa Freese Agend���E���/� � Director of Planning f i ;,1Y! Attachments: Proposed IUP Amendment, Ap r d B.y: Hearing Notiee, Mailing List USPCI has petitioned the City to amend the zoning ordinance in order to permit the disposal of coal ash at the Minnesota Industrial Cantainment Facility (MICF} . In considering this ordinance, �he Planning Cammission recommended that the Interim Use Permit be amended to address the handling of coal ash including monitoring and repor�ing requirements to the City. At the May 25 regular meeting the Commission recommended that the attached IUP amendment be considered by the City Council . In reviewing the 1992 IUP for MICF it was determined that a public hearing is required for an IUP amendment. If the prapc�sed permit is acceptable, it is recommended that the City Council set at public hearing for it at the next regular meeting. - The praposed permit sets up requirements for transport, dus� cantrol, and leachate monitoring. If the Gouncil wishes to consider additional requirements it woulcl be appropriate to discuss this prior to the public hearing so staff and consultants can incorporate requiremen�s into the permit prior to the hearing. Recommended Action: A MOTTON to set a pu �i� hearing for the USPCI Tnte�im Use Permit Amendment on June 15 at 8 :D0 p.m. or as soon thereafter as possible. City Cowacatl Actioaz 06/41/93.OQ6 Amendment to Interim Use Permit Agreement USPCI, Inc. 1993 fiHIS AMENDMENT, dated , 1993 is made by and between USPCI, Inc. , a Delaware Corporation (hereinafter ��USPCI") and the City of Rosemount, a Minnesota munieipal corporatian (hereinafter the "City") and is intended to amend the Interim Use Permit Ag�eement, dated March 19, 1992, between USPCI and the City (hereinafter the "Agreement" ) . RECITALS * USPCI entered into the Agreement with the Ca.ty on March 19, 1992 ; * Among other things, the Agreement identifies the types of wastes which USPCI ma.y dispose o� at the non-hazardous was�e containment facility (hereinafter the "Facili�y"} further deseribed in the Agreement; and * The parties to the Agreement are desirous of amending the Agreement to allow the disposai ot coal ash at the Facility under certain specified conditions . NO�i, THEREFORE, the parties agree to amend the �greement by adding a section after Seetion 12 of the Agreement to read as foliowss 12A. Disposal of Coal �+ash/Conditions: Despite the provision of Section 12 above, USPCI may dispose of caai ash at the Facility, but only pursuan� to the fc�liowi�.g conditions: 11 USPCT shall not use coal f1y ash as cover over waste when fill heights exceed the height of the perimeter berm a� the MICF. 2} During transport of coal ash to the MICF, trucks carrying �he a�h must be covered with `tarpaulins adequate to limit dusting. 3) USPCI shall. take adequate steps to prevent dust from coal ash disposal at the NlICF. USPCI may u�ilize, but i5 nat limited to, one or more o� the follawing methods for dust con�,rol: 1) eonditioning the caal ash by addition of moisture; 2) handling cQal ash when wind conditions are calm; 3} �,mmediately covering coal ash with eover materials. A11 methads utila.zed must be in con�ormance with all other provisions of the permit, 4) Cnal ash dispasal at the Facility must not result in leachate discharges to the Rosemount Wastewater Treatment Plant which fail ta comply with Industrial Discharge Permit requirements of the MWCC. 5) USPC� shall submit with its annual report a summary of the quantity (in tons and cubic yards) , type, and source ot coal ash deposited intt� the facility and shall provide an evaluation of the effects of coal ash on the chemical composa,tion of leachate discharged from the MICF to the Rc2semount WWTP. Except as specifically amended in this and other properly executed Amendrnents, the Agreement shall remain at full force and effect. IN in1ITNESS WBEREOF, the pa�ties have executed this Amendment as of the date first above written. USPCI, TNC. A DeTaiaare Corporation By: CITY OF ROSEMOUNT By: E.B. McMenomy, Mayor By: Stephan Jilk, City Administrator STATE OF TEXAS ) ) ss C4IINTY OF ) The foregoing instrument was acknowled�ed before me this day of , 1993 , by , its , on behal.f of USPCI, Tnc. , a Delaware Corporation. Notar� Public STATE OF MINNESOTA ) ) ss GOUNTY OF ) The foregoing instrurnent was acknowledged befflre me this day of , 1993 by E.B. McMenomy, MayQr, and Stephan Jilk, City Administrator� on behal� of the Citiy of Rosemount, a Minnesata munieipaZ corporation. Notary Public 2 i�� o osemoun� PHONE (61P)4234411 2875•145th Straet West,Rosemount,Minnesota MAYOR FAX (612)4235203 Mailing Address: Edward B.McMenomy P.O.Box 570,Rosemount.Mirtnesota 55068-0510 COUNCILMEMSERS SMeila Klassen �uj.�liC '�T�*lf�e James(Red)Staats V 1\ � Harry Wilicox De�ois Wippermann INTERIM USE PERMIT #�MENDMENT nonnfNisTanroR Stephan Jilk TO PERMIT COAL ASH DISPOSAL IN NONHAZARDOUS INDUSTRIAL WASTE CONTAINMENT FACILITIES Petitioner: USPCI, Inc. To Whom'It May Concern: NOTICE IS HEREBY GTVEN, the City Council of the City of Rosemount will hold a public hearing on Tuesday, June 15, 1993 in the Couneil Chambers of the City Hall, 2875 145th Street West, beginning at 8:0� p.m., or as saon thereafter as pvssible. The purpose of the hearing is to cansider an amendment to the 1992 Interim Use Permit for the Iviinnest�ta Industrial Conta.inment Facility operated by USPCI. The amendment pertains to the handling af coal ash and monitoring related to the acceptance of coal ash at the facility. The Zoning Ordinanee currently prohibits coal ash disposal and the City Council is considering revising that provision. The petitioner, USPCI, Inc., operates a nonhazardous industrial waste land disposal facility at 13425 Courthouse Boulevard and wishes to accept coal ash wastes at this facility. 'The property is located on the south side of Courthause Boulevard (STH 55} ea.st of US I�ighway 52 and north of County Road 38 is legally described as. A traet of land lying in Sections 19, ZO and 29, Township i 15N, Range 18W, all in the Gity of Rosemount, Dakota County, Minnesota, commencing at the SW corner of the East 112 of ihe Southeast 1!4 of said Section 19; thence east and southeasterly along the centerline of Caunty Road 38 to its intersection with the North and South Quarter 5ection Line of Section 29; thence north along said North and South Quarter Section Line of Section 29 and the North and South Quarter Section Line of Section 20 to ihe southwesterly right-of way line of State Trunk Highway 55; thence northwesterly along the soutkwesterty right-of-way line of said Highway 55 ta its intersection with the centerline of the Ghicago and Northwestem Transportation Company right-of-way; thence southwesterly along the centerline of said right-af-way to its intarsection with t6e west line of the East 1/2 af the Southeasi 1/4 of Section 19; thence south along said west line to the goint of commencement. PersQns wishing to speak on tYus Interim Use Permit Amendment are invited to attend tYus meeting on Tuesday, Tune 15, 1992 at 8:00 �,m. or submit written comments prior to the hearing to the Rosemaunt Planning Department, 2875 145th Stre�t West, Rosemount, MN �5068. Dated this 3rd day af June, 1993. Susan M. Wa1sh, City Clerk City af Rosemount Dakota County, Minnesota , (� � �( �ver�t�ivigs �omtng `U�,� �ll,osemaun��? . . . � . A . . � . . � . . � � . . . . ► •.._ ....'.... . � t � 1 USPCI, INC. USPCI INTERIM USE PERMIT AMENDMENT' MAILING LIST t. Koch Refining Company 34•01900•010-02 P.U, Box 2256 34U19UU-010-DB Wichita, KS 67201 34-01900-011•10 34•019d0•010�62 34-01900•0}0•80 34-42QOQ-010•35 34-02000•010•3$ 2. Chicago & NW Trans Co 34•019U0-010•50 1 N WSTN CTR 34•01900-010•82 Chicago. IL 60606 3402000•U10-27 34-02000-010-75 3. Paul J. Nieland 34•01900-010•52 13250 Giayton Avenue E Rosemaunt, ARN 55068 4. Metro Waste Control Cammission 34-01900•Q1Q•86 Mears Park Centre 230 E Ffth Street St. Paul, MN 55101 5. Orrin Kirschbaum 34-p20U0-fl10-01 _ 13220 Ooy1e Path 34•D2000•O10•11 Rosemount, MN 55068 6. Joseph M. & Julie A. Simones 34-0200Q-OiQ-08 13273 Pine Bend Trail Rasemount, Mn 5506$ 7. Pine 8end Devetopment Co. 34-fl20Q0-010•]3 % Melvin �. Astfefard 34-02000-010-25 1200 Highway 13 West 34•02f100-Q10-28 Burnsville, MN 55337 3402000-010•39 3402000-010-82 34•0290Q-010•01 34-02900•014-2U 34-02900-Q11-25 34•0290C1-Ot0-35 34•03000-010-01 34-0300D-010-19 8. USPCI, Inc. 34•02000-011-50 Suite 500 34-0200U-011•60 515 West G�eens Road Houston, TX 77061•4524 9. Ninth Street Prop.,lnc. � 34•020Q0-010•37 One Commerce Green 515 W Greens • Suite 500 Nouston. TX 77U67 1�. D. W. Sevarson 34-02000-01D-77 3389 140th Street East Rosemaunt, Mn 55068 . „ 11. James H. Kromschroeder 34•02U00-010-86 13625 Conrthouse Bivd • RR 2 Rosemount, Mn 55068 1?. Masahiro & Brenda Sugii 34-OZQ00•Ot0•88 13701 Courthouse Bivd Rosemount, Mn 55068 }3, Rich T. Burger 34•029Q0•010-]0 M. G. Ast4eford 1200 Highway 13 West Burnsville, MN 55337 14. Catvin V. & Eleanor C. Twining 34•02900-010-11 5480 142nd Street East Rnsemount, Mn 55068 15. �ala B, & Bettp L. Agre 34•029Q0-01D�15 14175 Eilers Patb Rosemount, MN 55068 16. Raymond A. & Roseila Rahn 34-Q300U•O10•09 3855 145th Street East 3403000•010-25 Rosemount, MN 55068 34U3000-01031D 17. Marlin W. &Joann Rechtzigel 3d•03000-013-35 14727 Glayton Avenue East Rosemount, MN 55068 . 18. The Sol6erq Construction Co. 34•03Q00-010-4U 13245 Ctayton Avenue Rosemou�t, MN 55068 19. Spectro Alloys Corp. 34-33400•010•dt 13220 DoyJe Path - Box 10 34-3340D-U20•Ul Rasemount, MN 55068 3�•334D0-030•Ot 34•33400-04U-01 34•340Q0-Q40-02 34-34Q00-050•02 20. HoAenback & Nelsan, Inc, 34-33400•050-fl1 7700 Weniworth Avenus South 34•33404-060-01 Minneapolis, MN 55423 34-33400-07Q•01 34-33400•Q80-01 -22. Eagle Sanitation, Inc. 34•33400-010-U2 Box 228 34•33400-020-02 Newport, Mt� 55055 34-33400-030-02 Z3. Rex Cra#t APPLICANT USPGI Suite 210 1445D Sout6 Robert Trail Roserrtount, MN 55068 R .� � 1 CiL3' Of�OSeIYiQllrit Ordinance No. B- 29 AN ORDINANCE AMENDING ORI3INANCE B CITY C)F RQSEMQUNT ZONTNG �RDINANCE THE CITY COUNCIL OF THE CITY QF RQSEMOUNT, MINNESOTA ORDAINS AS FOLLOWS: SECTIQl�' 1. In Section 3.2 DEFINiTI�NS of Drdinance .8 - City of Rvsemaunt Zoning Ord.inance the definition of l�Trn-I3azardous Industrial Waste is amended to read as follows: Non-Ha.zardous Industrial Waste Salid waste generated fram an industrial or manufactt�ring process, Non-hazardous industrial waste shall not include: incinerator, resource recovery or power plant ash, except one hundred percent (100% coal ash, or 6y-product from ttie processing ar recycling of such ash; liquid wastes not praeessed at the facility; sewage sludge, including treated or digested sewage sludge; PCBs; infectiaus waste; hvusehalci garbage ar refuse; non-hazardous industrial waste that is economically feasible to recycle; radiaactive or nuclear waste; rendering or slaughterhouse waste; or hazardous waste. SECTI4N 2. T'his c�rdinance shall be effective immediately upon its passage and publication accordi�g ta law. ADOPTED this 1st day of June, 1993. GITY OF ROSEMQUNT E.B, McMenomy, Mayor ATTEST: ' Susan NI. Walsh, City CIerk MAY 2$ ' 93 11 : 50 FROM BARR ENGINEERING TO 4235203 PAGE , 0�2�603 r � ` 1 � � ��� � � � � � � � � . � �fK�HIL21lpg��ll�l�l�y 8�t70 NormBn Cente+'Drive Minr�esp�Crs�MN 55437-f 026 Ptwne: {612)832�260l1 fa3r: (Sf2)83S-0i8S May 28, 1993 Ms. Lisa �'reese City o� �.Qsemount 28�5 - 145th Street West Rosemount, MN 55068 Re: Council Mernber Sheila Rlass�n Memcir�nclum to City Acl�ainistrat�r Steve 3ilk Dated M�.y 25, I993 Rea USP�I Caal Ash Text and IUP Aiaendment R�quest D�ar Ms. Freese: � have reviewed the questions contaiAed in the above-refezenced docuiaant and have grepared brief xesgonses. Responses are nivabered to correspond to each of t2s. KZasseA's comments, and �re as fallows: I. In oz�der to ensure that the ash tiisposed of at the MICF fa�cility exhibits t3�e chemical and physical charact�risti�s 4f cOal ash, I suggest two possible approaches as follows: �) Cqal a�h froia various faciliti.es �ou�.d be accepted pxovided no other utat�rials {i.e., coal tar, oxide box tiller, etc,) was b�.�nd�d with the £u�l tkxat produced the ash. �o ascertain Lhat this was the case, aommunication directly �+rith the plant praducing the �sh iaay be required. b) Alternately, since powez p�ants do on occasion blend other "fu�ls" with coal w�.th na dis��rnable cDanges in ash char�acteristics as a r�sult, USPCY could be required to present baseline physical aAd chemical char�ct�ristics of the coaZ astt from each plaut dis�+asinq of ash at the i�CF. 2f other mAter�.ais were to be blended with the coal at the plazat, US�CT couZd b� required ta submit to the city resu�.ts Qf physic�►l and chemical characterizatic�n of th� ash from a tes� burn, priar to acaep�ance cr� the altered ash �or disposal. 2. I agree that it would be �ppropriate for vSPCI to indiaate from which plants they ar� coasidering acce�ting a�h. If no plants hav� yet b�e.n identifi�d, then �dditianal infortaation �hou].d be �ubrnitted a� a condition cf th� permit prior t4 dispasal of �sh at the MIC� {i.e. , USPCI sha11. aotify th� City af Rosemount r�ot less 'than days in advarsce of the ace�ptance of coal ash for di;�posa3. a�. the M�CF from a plant not currently dispas�.ng af` ash at the faci.i.it.y. Nvtifica�ion sball ittclude the foZlowing componcnts. . . . . . } . I suggest the Ci.t�y work with the State a�nd Cour,�:x to ccerdinata repc�rting r�quests and limit duplication of effort5. MAY 28 ' 9� 11 : 51 FROM BARR ENGINEERING TO 4235203 PAGE . 003rpp3 ' . � � 1 Ms. �,isa Frecse May 2$, 1993 Page 2 �. The 2�+tPGA is d�veZoping rule� d�sa.gncd to cc,ntroi Air Toxics, an� camponen� of whieb is u►ercu�y. 2�he Air fioxics rulemakiny process i� still ia early stages and theref4ra it is difficull� ta Qrediat whei'� or if such rules Wi31 be i.mplem�ntec�� ,A reexami.��tian ciau�e cc�uld be Gamt»,ned with not�,fication requirements suggested in r�$pnns� ntt�nber 2 ab4v�. 4• Refer to respc�nse number 2 above. 5- As �.ndicated in Barr's correspoadence dat�d Apri1 8. 1993, RDP ash tex�ds to be incousistent in nature. It is sornetimes otaly p�rtia�,3.y combusted, resulting ia �missians of inetha�ie and hydrog�n sulficie gas after dispasa].. Al�hough sy�te�as can b� designefl tcs prog�rly handle snah emzssions, the ta�aility Ziner does nqt meet current elesign standards �or dispas�l of RDF ash. �h�refor�, i�t is appropriat� for the City to maiutaim i�s pvsitian on not $llowiug dispogaZ af RDF 2►sh at the M�CF. 6. No respoase z'eqtlired. An ad�i�tianal question poaed by another counci}, m�aber r�Iates ta the poasi�ile i.iapacts af suifur couepounds and mercury Qn the facility lia�r. Current literature prcvided by manufacturers of High Den�ity Polyethylen� (gDpEj geomembranes i.adi�cat�s little ox no i.mpact Qn th�- HT�PE compcanent of �he l.�.t�er from contact with mer�ury ar sulfur. Impacts of inercury or sulfur compounds on the el�aY cosnganer,ts of the facility linex are mere diffieult to eva3uate, Testing �uch r�s p���i�,ity t8sting, determinatian of �$t1an �xchange cagacity, or �lay crystal structure analysa.s usi�q �canaiAg �Zectraa micro�cope pho�4gr�phs may be rac�uired �o evaluate imgacts on clay. However, at the cori�entrations that ecs�ld zeasanab�,y be exp�ctezi, impacts of inercury ox sul�ur c4mpc,unds on the in.tegrity of the clay companent of the Ziner wou3d be exp�cted to be negligible. As we discltsaed on Thta,rsday. I plan ta attez�d the council meeting at 8:00 P.M. on Tuesday. Jt�ne l. �f you have any qu�sti.ans priQr tQ tbat time, p�ease feel fxe�e to ax11 a� at 832-2871, Sincerely, ; �i����.� � �- .��''�.�',� Thom�s J'. a1�: due p , .E. TJR/tmk 23\19�2�0`�+F8.LTFt *� TOTAL PACaE .003 �� � I � + ti . .� . �. . � . . . 7 . . . � . . . .. . M�y 25, 1993 I To. Steve Jilk, City Administrator � From: Sheila K{assen, Councilmember � Re: USPC}Coal Ash l"ext and kUP Amendment Request Steve, I have had discussions with Frank Hornstein, Executive Director of the Ciean Water Action AlGance in regard to U�PCI's request for approva( to take coal ash at their MICF. From thase �iiscussions and reviewing Barr Engineering's report I feei the foilowing poin#s should be addressed and ask that you have staffi look into thern. 1. Make sure the ast� being received is 100°lo coal ash. lt is my understanding that the 3M Chemolite plant aiso burns solvents and other wastes. {n addition, the NSP A.S. Ktng piant has appl'+ed #or a permit to burn coal tar and oxide box fitler. {See attached articie;} This could effect the chernicai make-up of the c�oal ash, 2. Limit eoa! ash to plants within the State of Minnesota. Again, it is my understancling that the NSP piant in Big Stone, S.D., is undergoing a demonstration projeet co-firing Refuse Derived Fuei (RDF} with coai. This mixture of garbage to coal is between 1�%0 and 30°Jo. Here, too, if this becomes a trend in Mir�nesota it may effect the caa! ash content #rom the plants the MICF is senricing. 1 wou{� suggest USPCI inforrn us of what plants they are dealing with and what the plants burn or will be burning. 3. 1 am told the PCA is going thraugh a rule making process to require coaf burning facilities to instaif scrubbers to eiiminate Mercury from their ernissions. Whife th�s is good for air quality, it cauld put rnore Mereury in the ash, which could effect the coal ash content. Here, i suggest we find out more about this new regulation, when it will ga into effect, thereby knowing when to re-examine the coal ash content to see if it is sti11 within non-hazardous limi#s. We may want a re-examinatian c{ause regardless of this new regulation. 4. We may'want to haue an approvai process over what piants the MlCF is servicing. Back to the A.S. King plant...if the plant is aliowed to burn the cQal tar and oxide box #il�er, it will result in �missions high�r in suifur. This eould mean the ash cc3ntent wii! be higher in suifur which cou[d cause a greater�effect on the concrete structures of the MiCF. 5. for my comfort level, 1 would Iike to see stronger wording making sure RDF and MS1N is unacceptable at the M1CF so it is very ciear that al1 parties recognize this as a "specia{" waste which the M1CF is not buitt to handfe nor buiit with the intention of handiing, and ta reaffiirm that this is a nan-hazardous waste containment facility. 6. I believe the Barr Engin�ering r+eport assumes the ash wi�! be 1�0%a coal ash. lt also mentrons the cancerns above, i.e. the effect of sulfur on concrete, not taking .! } � . . � � . .. . . � . � . . � . . .. � . � . . � .. � � . � . MSW, manitoring the facilities serviced and being carefu! not to mix the coa! ash with other substances that couid eause a change in the chemical make-up. it ais� addresses operational cancerns regarding dust, more sludge in the leachate that could efifect the waste water treatment plant, and possible cornbustion of hot ash. 1n closing, f am requesting the points presented be addressed either in the text ar the tUP. I would aiso suggest we have a discussion to re-acquaint ai1 concerned with the m4nitoring and reporting requirements af the MICF. If you have any questions. please feel free to call me at 423-4391. cc: Council Pianning Commissian Planning Staff Don Chapdelaine, USPC1 I .t . ; . 1i r� �' . 1"�, r . ... � � . . . U . :, �. �'�j' , � � � � . ;I�ila � ��.e', � . r�. � �,.� 3B_ � F, `?'` ;. '� _ :�s'r=,r — . �Sp �� v�rer�p�ant-_ ;4:� pA�:p, . .: . � .,; .. �: `��,�:�: .. ��'t`�cc�uld cut _ . - - .� ' �.� �� . � llut�or�- ... iiicrease:po � _ �:�.�. , ; : }- ■ he state's dirtiest power plant� : �:• : received a isew permit from �the• y.. . j Mi�es°ta Pollution.Control Agein-- �, j �y�oa�Tuesday.�that could;both.i'�' t • :air �'�. duce arid increase the pollu�o�. :; g'• roduces: "'". :�,— _�.,: � t;< n it P rmit wtll allow Northern :� ; �;� The pe . � �_ oStates Power�o.,the owuer of�lie , 3t AIan S. Ring Plant in Oak PaYk ;.� ; � Heights.�to°clean. up;old- wast�es . •� :;`y.� w�iich -�� rr. ;d beianging' to. Minz►egasc°�.. ,,. s_�1 �. �l_ are leaking cyanide into the NIi's- � � t River tn Min��i�� :-�- . : �y sissipp', �.e a h�ariug. ° � Se Aad•�t will �1 �.ative law, . ' befare..:� a� � ' C :ct judge to see if the plant s permif ze- should be made. .more � stnct,:; � ': t - c e. �p r a m p t i n g a g e n c y.taoard men�ber� ; : �, tad Bill Urseth to sap�it is a.waste.o f: . ,� _, uld money:that will not improve f he . �� �: . . for environment beeause of new.fed �. eral laws. �r` '' down�thss. ' yow `�The'canfusion breaks iin way:.'The new permit will cut b�^ o f 2,278 tons the amaunt:of sulfur• � the dioaide -- one of the�p��, . get �ents of acid rain — �r.r :. . tbe release into the aiz each y .nd i At the same time, the new per. • .d of mit allows the Ring plant to'miX' �ught in coal tar and oxide bog filler;;�= • ; �. residue�le#t over from the days ';, j. . . c t i n g whea�Minnegasco made coal gas. � after However,that�is h ig h in s u l f u r.a n d.. : , . :il of- could'result in an additiana1626 to � linne=: 725 tons o# sulfur dioxide going =, ' �,. into the.air,:.. . . - •� t � .. - ;�: ` „ 'L-L. O,YL,. �i�e . . . .. . . , '�a� ��:: �`�1 ,�' �i� . . ,{ �;;1 � s . , �, , .�x,y,�-��. ::E �'s* w .: ':' .. . �.� � ;l � ;'�.'�.1 �� �,���,�. { •`�) �. . . . . . . �'*,� . ...ie� i' ::z:.' .. 45�� `�a i����� �� y 3 . ^.�A.1 . . .. d t,- ,�'� 7 ''"'.�' ✓: ' � � ';i� � H � . �. � r.i. • . �'•�� .� � �M. a� i � � � � � . . � . � a '���.�'.� � 5 9 � ' � ... . 1 .♦�I.;.4zr1 � y! r- ;:3'rL�.S�>. � ' _ .. . . .jlf,.a,tr� :�r�. vR.:'+:1 ..�� - . . . . . . . . � a��' � . � . � . � � . � � t , . t.'�� � � � • �'� �� . . :� �.=.. �:,� � . : ai f , , � � � ,, ua �t=-� ' ;r� � ,�-:, , . � 't� ;:��• . �� ,no � , , City nf Rosemaunt Executive Summary for Action 4 Planning Comrnission Meeting Date; April 27, 1993 Agend� Item: USPCI Text Amendment Petition Agenda Sect�an: NEW �USINESS Prepared By: Lisa Freese Agenda Nfl.: Director of Planning I'TEM NC}. 11 Attachmentss Zoning Ordinance Excerpt, Barr Engineering Approved Byz Report, Correspondence from MWCC, APplicatic�n & Supporting Materials Attached is the report fmm Barr Engineeriang regarding the request to disposal of coal ash in the Minnesota Industrial Containment facility. The report identifies no major issues with allowing coal ash to be disposect of in this facility, In the report Mr. Radue outlines that some additional actions be taken by the City if the acceptance of coal ash is cansidered: - Dust Control (wetting materials, covered transport, limiting height of fly ash fill) _ Leachate Monitoring Based on Mr. Radue's analysis, Planning staff believes a favorable recommendation on this zoning ordinance amendment wouid be appropriate. If the Planning Comrnission agrees that it would be appropriate to attach the eonditions suggested by Mr. Radue it would be necessary to add an addendum to USPCI's existing Tnterim Use Permit (IUP). This addendum cari be prepared at your directian and placed on the May 11 Regular Meeting Agenda for your review. Planning staff recc�mrnends that the public hearing before the City Council on the Text Amendment be set far May l8 and that final recommendations on the text amendrnent be made concurrently with tlae IUP addendum at your next meeting. Recommended Action: A MCJTION to recommend that the City Council set a Public hearing on the Zoning Text Amendment for May 1$, 1993. - and - ' 'A MUTI�N to direct staff to work with the City Attorney to deveiop an IUP addendum relating to the handling of coal ash per Barr Engineering's recommendations. Planning Commission Action: 64-27-93.011 J 1 1', . � . � ��.�,. a.�r Engineering Company 8300 Norman Center Dr'rve I Minrteapolis,MN 55437-1026 Phone: (612)832•2600 ' Fax: (612)835-0186 Apri 1 8, 19 9 3 Ms. Lisa Freese Director vf Planning Gity of Rosemount I P.O. Box 510 2875 - 145th Street West Rosemount, MN SSOb8-0510 RE: USFC2 Request to Accept Goal Ash Dear Ms. Freese: As a follow-up -to Barr's proposal of March 12, 1993 and your work ' authorization of March 29, 1993, Barr has completed review of USPCI's proposaI. to accept coal ash for disposal at the MICF in Rosemc�unt. Barr's work on this I project included the fallowing: - . Reviewed USPCZ App],ication, "White Paper", and Waste Acceptance Plan - ■ Prepared surnmary Report of Review Findings ■ Id�ntiEied Potential Issues of Concern . Pre axed Recommen a � P d tions The attached pages summarize the findings of the review and present Barr's I recommendatians. I look forward to meeting with you on Thursday �o discuss any questions you may have. 5incerely, , / /'c.��"�J � .�Gl�!z.�2._..--- Thomas .7� adue, P.E. TJR/cet Enclosures c: - Bill Lauer, Dakota County __ 23\19\260\LF.LTR . -- : . l . � , , � � 1.0 INTR(7DUCTION On March 5, 1993 USPCI, Inc. (USPCI) requested an amendment to th� City of Rasemount zoning ordinance text to allow disposal of coal ash at the �iinnesota Industrial Containment Facility (MIGF) . As requested by the Gity of Rosemount, and in accardan�ce with Barr's proposal af March 12, ;1993, Barr has reviewed the USPCI Application, "White Paper" , and Waste Acceptance PSan. These documents were reviewed in light of the discussion questions identi£ied by the commissioners at the March 23, 1993 Planning Commissian meeting. The general questions identified are surnmarized as follows: . What are the physical and chemica2 characteristics of coal ash? . How can the City ensure that approval of the USPGI plan will resu3.t in dispasai of coal ash but na other unpermitted types of ash? . What types of chernical reactions could occur between the coal ash and ather waste types disposed of at the site7 . Are there envir4nmental benefits associated with aecepting coal ash at the Minnesota Zndustrial Cantainment Facility (MICF}? In addition to the questions identified during the planning commissian meeting, Barr identified the following additional questions: ■ Will dust emi5sions from the facility result froan ash disposal? . Does disposal of ash have the patential to cause difficulties with treatrnent of leachate fram the site? During review af available documents and preparation of this report, it was assumed that USPGI would consider accepting coal ash from facilities such as the 3M Chemalite facility, from Northern States Pawer Company Metra area pla�ts (i.e. , Riverside, Black Dog, High Bridg�, �nd A.S, King), and other 1oca1 industxies tbat utilize coa2 far heat or power generation. 23\19\260\LF.LTR\CET 1 . � � � � i � . � ���. 1 I 2.0 DOCUMENT REVIEW USPCI has requested madification to the Rosemount 2oning Ordinance to allaw I acceptance of coal ash at the Minnesota Industriai �antainment Facility (MIGF) . In addition to the request for zoning ordinance modification, USPCI provided additional documents which are summari2ed and suppl,emented by additional information in the following paragraphs. 2.1 White Paper The "White Papex" submitted by USPCI presents brief overviews of the process that produces coal ash, the quantities produced in the U.S. anr►ually, the rnajor constituents and potential environmental impacts from the caal ash, and alternative uses for coal ash. The primary environmental concerns related to coal ash disposal are the potential for contaminatic�n of groundwatex or surface water by metais or suspended ash solids, and the potential for air pollution from airborne ash particles. The physi.cal, mineralogical, and chemical properties of ash depend on the composition af the pa�ent coal, and the boiler design and boiler operating conditions. Composition of coal a�h, which is the noncdmbustible fraction of coal, varies slightly, while ash constituent concentrations vary more widely. I The fine particles remaininq after caal combustion (f1.y ash) generally contain higher cancentrations of trace elements than the c�arser fraction (bottom ash and slag) . Typical properties af coal ash are summarized in the folldwing paragraphs. Phvsicai Characteristics Fly ash typically is in the silt to clay si�e range, while bottom ash and boiler slag generally is in the fin� sand to fine gravel particle siae. Minimum dry densities for ashes generally are in the range of 45 to b5 paunds per eubic foat. Maximum dry densities typically fall within the range of b5 to l0U pounds per Cubic foot. I' 23\19\260\LF.LTR\CET 2 � . � 1 � � � � � . � . . ` Permeability refers ta the rate at which water will seep through a materiai in a given periad af time. Permeability is influenced by the size and shape of the particles, the degree of cc�rnpaction, and the viscosity of the permeant. Bottom ash permeabilities generally fall in the range of 10'' to ll3'' cmisec. (similar to gravels and sands) while fly ash permeabilities fall witha.n the range of 5 x 1Q'S to 10'8 cm/sec. (similar to silts and clays) . Chemical Gharacteristics Oxides - Oxides of Silicon {Si) , Aluminum {Al} , and Iron (Fe) comprise 95 to 99 percent of coal ash. Cdal ash also contains trace amounts of Calcium {CA3, Magnesium (Mg) , Titanium {Tij , Sulfur (S), 5odium (Na) , and Potassium (K) oxides, as well as very smaZl quantities of up to 50 other elements which may include Boron, Selenium, Chromiurn, Arsenic, and others. Polycyclic Aromatic Hydrocarbons (PAxs)' - The carbon compounds of most interest in coal ash are the PAHs. They are produced as a result of incomplete combustion of fossil fuels. Studies perfarmed by the �lectric Power R�search Institute (EPRI) and others have generally found that PAii compounds in coal ash , are found at concentrations tfiat pose little concern for potential ground water contaminatian according to EPA critieria. Dioxins and Furans - Diaxins and Furans refer �o families of chiorine and benzene based compounds that are present ir► the environment as the result of manufacture of chemicals such as some pesticides, and frorn a variety of combustian saurces. The comhustic�n of coal does not appear to result in the productian of Dioxins or Furans above current analyti�al detection limits. Radionuclides - Radionuclides are naturally occnrrinq in coal and coal ash, but at very low ].evels. The available data suggest that coal ash is enriehed with some radionue3ides as compared to background concentrations, but at leve2s considerably belflw federal standards. 23119�2601LF.LTR\CET 3 � + i'' r 2.2 Waste Acceptance Plan ' The USPCI waste aeceptance plan poses a series of questions for determina.ng acceptability of waste for disposal at the MICF. The following are the questions fram the Waste Acceptance P2an, followed by the probable answer to the question �� as i� relates to coal ash. In some cases, the answer to the question must be I' evaluated on a case-by-case basis, ' 2.2. 1 Is the waste one whieh is listed as hazardous by the United States Environmental Protection Agency {EPA)? Coal ash is not 3.isted as hazardous waste by the EPA. 2.2.2 Does the waste contain free liquids? Coal ash may contain free liquids if it is remaved from the plant using a slurry system, or if it is rem�aved from the flue gas �, using a wet scz�ubbing process. This must b� determined on a case-by-case basis. 2.2.3 Is the waste reactive? Goal ash is not reactive. 2.2,9 Is the waste corrosive? Coal ash is not corrosive. 2.2.5 Does the waste contain radioaetivity? Coal ash contains radiaactivity, but at levels below federal , standards. 2.2.6 Does the waste contain u�►acc . ' eptabl� organic substances? Goal ash does not contain unaGc�ptab2e organic suhstanc�s. 23\19\26U\LF.LTR\CET 4 ! . I , . . � . � . � . ` 2.2.? Is there conclusive evidence that metals eyaluated under the TGLP are not present? Caal combustion wast�s including fly ash, bottam ash, and slag generally do not leach metals during the TGLP test to the degree that the ash would be elassified as hazardous under this ral�. However, results of the TCLP test must be evaluated on a cass-by-ease basis. 2.2.8 Ts there any other reason why the waste should nat be accepted? USPCI must consider characteristics of other wastes accepted at the MICF to deterrnine if the resulting mixture would be cause for not accepting tfie coal ash. Specific facility design characteristies must also be considered' in determining if coal ash should be accepted. For examgle, leachate from coal ash which is high in suZfate may cause damage to any cancrete structures it cantacts at the site. The damage results from sulfate reactidn with the calci.um in the concrete, causing softening and gradual deterioration of the concrete. Furthermor�, some adjustment to opera�ions may be required to handle increased surface wa�er runoff that ean result from disposal of coal ash, and in particular ths f1y ash portion of the coal ash. 23\1��260\LF.LTR\CET 5 � i . r 3.0 POTENTIAL ISSUES OF CQNCERN 3.1 Fugitive Dust Emi.ssions The potential for wind erosion and fugitive dust emissions from coal ash depend on climatic faetors sueh as precipitation, evaporation, and wind spsed, and on 5urface textur� and moisture content of the ash. Vehicular movement on the ash can also increase the potential for dust generation. 3.2 Leaching C4nstituents of greatest concern in coal ash leachate with regard to adverse water quality impacts t.ypically include boron, selenium, total dissolved solids, and sulfate. Ghromium and arsenie are also of concern for some coal ashes. I 3.3 Hot Loads Delivery of hot ash laads to the MI�F could cause comlaustion of ather materials -disposed of at the facility. Disposal of coal ash at the MZCF is not likely to have any direct environmental benefits. The primary environmental benefits to coal ash dispasal are likely to be indirect in that the MICF site may provide greater environmental protection than that provided at the location where the ash was previously disposed. 23\19\260\LF.LTR\CET � � � ` cambustion of municipal salid waste are less predictable. As a result ` of the visual differences, routine sit� inspections typically can detect the dumping af unauthorized ash from munieipal solid waste incineration or ather facilities. Furtherznore, ineornplete combustipn of refuse cleriveri fuel can result in the generation of inethane and hydrogen sul.fide gas after ash disposal. Due to the inconsistencies inherent in ths nature of ash from municipal solid waste incineratars, it wou].d be appropriate for the Czty of Rosemount ta continue to forbid disposal of sueh ash a� the M�CF. � � -3t. � �. ��. - :;�-. . . .__ =�: . . ��.:.�, ... . . . ,:: . �- . -- .._ `�yy�. ,�� - ,.�Ay ._ - _ _ - _ _ _ _. _� ,�... _. ,_ _ �� _: .. ,.. . _��.. . ._. �.._ 3.:,..- . .:..- _.'�. �...�. - . �.��. ... ..�. 23\19126U\LF.LTR\CET g � f ^ combustion of municipal solid waste are less predictable. As a result , of the visual differenees, routine site inspections typically can ' detect the dumping of unauthorized ash from municipal solid wast� incineration or other facilities. Furthermore, incomplete combustion of refuse derived fuel can result in the generation of inethane and hydrogen suifide gas after 'ash disposal. Due ta the ineonsistencies ' inherent in the nature af ash from municipal solid waste incinerators, , it would be appropriate for the City of Rosemount to continue to ' farbid disposal of such ash at the MICF. ` 'I _ � - �_ ��: ..�: -.....--_�`' ' ...� ° _ - _ - - - - - -�= _ _ _ _ - - � _ _ , _ _ �y `_ =-�. - 23�15\260\LF.LTR\GET g . , , . No: �Date: City of Rosemount ZONIN� 4RDINAI�tCE TDCT AMENflMENT PETlTION APP�icant; USPCI, Inc. Phone: 438-150f7 Address: 13425 Courthouse Blvd, STATUS OF APPUCAt�!`f: . � Owr�►er Buyer Lessee OTHER: LOCATION: Lat . Block . Addition Street Address: �-3425 Courthouse Blvd. Metes 8� Baunds {�esc�iption Attacheds Yes Survey ar Ptat Flan Attached: A#fected Section(s): All RERSON FOR REQUEST: 1. USPCT �uld �.ike �o aceept non-hazardous ash from the c�ombustian of coal, while keeping in place the prohibition against rrnanicipal soli.d waste incinerator ash. 2. 3. Signatu�e of Applicant: FO OFFtCE USE ONLY �PPiication received by: ` Date: li'�-�'-�--'-��,�� o�o fee; �_,;��""' How Paid: �- �� � Date: � Ptanning Commission Actfon: Dare: . r , r' � I USPCi MICF S�te legal Description A tract of land lying in Sections 19, 20 and 29, Township 115N, Range 18W, all in the City of Rasemount, Dakota County, Minnesota, commencing at the SW corner of the East 1/2 of the Southeast 1/4 of said Section 19; thence East and Southeast�rly along the centerline ofi. County Road 38 to its intersection with the North and South quarter section line of Section 29; thence North atang said North and South quarter section line of Sectian 29 and the Narth and South quarter section line of Section 20 to the southwesterly right-of-way line of State Trunk Highway 55; thence Northwesterly along the Southwesterly right-of-way line of said Highway 55 to its intersection with the I,' ce�terline of the Chicago and Narthwestern T'ransportation Company I' right-of-way; thence Southwesterly along the centerline of said right-of-way to its intersection with the West line of the East l/2 of the Southeast l/4 of said Section 19; thence South along said West ' line ta the point of commencement. � _ I ; _ _ � . p � . - - - E_.�- . :_. ;:. . :��:-._ ' _ � - _ . ` . . r'': — _ - _ __ __._ _ __ _ _. , - , . -_ - - - --- - ---- -=— --�- . , Ordinance B--Defini��on , t Width The width measured along che front lot line or street line. ,�taua#'actured Home "Manu€actured home" rneans a structure* transportable in one or more ' ' sec[ions, which in the travelin� mode, is eigbt (8} body feet ar more in width or 4Q body feei r-�-� or more ia leagth, or, whezt erected on site, is 3?A or more square feet, and which is built on . a permaneat chassis and desigued ta he used as a dwelling with or withtsut a permaneni � foundation when eonnected to the required utilities, and includes the plumbing, heating, air . cQadiuoning, and elec[rical systems coataiaed therein; except that the term includes any structure which meets all [he requirements aad wz[h respect to which the manufacturer voluntarily fiies a certif�cation required by [he secretary `and compPies with the standards established uader this chapter. Manufactured Home Park Any premises on wluch fwo (2) or mare occupied manuEaetured homes are located. ManvfactvrinQ. Custom The praductioa and sale fln the premises of hand manufactured products involving only the use of hand taois and domestic �echanical equipmeni. Minerai Extractiqg The extraction of sand, gravel, rock or o[her such material from the tand. Montessori Schaol A school for chiIdren where the fundaznenta! aim is self-educatioa. Motel A building or group of attached or detached buildings under cornmon ownership containin,g eight (8) ar more guest or sleeping rooms which is used or intended Ko be used primarily for the accommodation of tran.sient automabile travelers. This term shail include � buildings designated as auto ersuru, tourist courts, moCor caurts, motar hotels and similar mames. Motor Freight Terminal A building or area in which €reieht brought by motor truck is assembled andlor stored for routing in igtra-state ar inter-state shipmen� Muitiple-Familv Uwelling See Dwelling, Multiple-Family. / t;'^ Nan-Conforming Use .r'� huilding o; use of land which does not confom► to the regulations o€ the district or zone in which it is situated. Non-Hazardous Industrial Waste Solid waste gener2�ted from aa industrial pr manufacturing process. Nan-hazardous industrial waste shall not inctude: incinerator, resource recovery or yv ower lant ash, or by-groduct from the processing or recycling of such ash; liquid wastes not processe ai the facility; sewage sludge, ineluding [reated or digested sewage sludge; PCBs; infectious waste; household garbage or refuse; non•hazardaus indusuial waste that is economically feasible to rerycle;radioactive ar nuclear waste;renderin¢or slaughterhouse waste; or hazardous waste. . Non-Hazardous Indu�,trial Waste Containment Facilitv A faeitity that accepts and land disposes af only non-hazardous indusuial waste. The faeilizy may accept non-hazardQuS industrial liquid waste if such liquids are processed to insure no free liquids are land disposed. A €acility sball inciude coatainment cells and all other appurtenances necessary for i[s operation. Nursez�- School A school for children of preschoal age. � Nursin� Home An extended or intermediate care faality licensed or appro�°ed to provide full- time convalescent er chronic care to indiyiduals whq by reason oF adt-anced age, chranic illness or infirmiry, are unable to care for themselves. Ot'fices. Busines� A building(s} in whieh business of a non-retail nature and clerical services aad duties are earried out, includin�corporate affices, banl:s, credit unians, insurance and re21 estate t�ffices and includir►g multiple-tenant bffice buildin�. Of#ices. Prafessianal A building in which professional and mana�cment duties and services are ca�zied put, including medicat and dental clinics and offices; psychiatrists and psvchaio�ists ``�- offices; architectural, en¢ineering, planning and legal ofCces, and simiIar uses. � 6 t ` USPGI . � A Sul��i�i of Union Pa 'ic Corporation March 5, 1993 Mr. Stephan 7ilk City of Rosemount 2$75 - 14Sth Street West P.O. Box 510 Rosemount, Mn 55(#�i8 Dear Mr. Jilk: USPCI, Inc. is requesting an amendment to the Rosemount Zoning Urdinance text to allow the acceptance of coal ash at the Minnesota Industrial ContainmenC Faciiity (MICF). USPCI is '�, making this request because it believes that coal ash is a non-hazardous industrial waste of the '', type that MICF was designed to effectiuely contain with no harmful effects tc�the envimnrnent. , As you recall, the pertinent portions of the zan�ng ordinance were written while there was debate I over the permitting of the Dakota County Resource Recouery facility. There was concern that a State-of-the-Art I.and Disposal facility such as the MICF might `be used for municipal �, incinerator ash dispasal if the incinerator was constructed. The City took stegs to alleviate this ', public concern, with the support of USPCI, by �xcluding ash from municipal waste incineration or resource recovery from being aceepted at non-hazardous industrial waste facilities in , Rosemount. '� USPCI understands the intent of the ordinance to prevent ash from municipal waste combustion, generated at incinerators and some power plants such as NSF's Red Wing facility, from being I sent to the MICF. Ash from coal-burning power plants, however, has taeneficial properties that are desirable in the chemistry af eontainment cells. II� In many areas, coal ash is used as a solidi.fication agent to bind liquid waste prior to disposal. II, Coai ash is cunently being disposed of at other facilities in Dakvta County. Under MICF's ', Waste Acceptance Plan, any cc�al ash that is accepted at the facility must undergo the same , rigorous sampling and testing procedures that any other waste must undergo grior to acceptance. , USPCI feels that this is a waste stream that may be ben�ficialiy re-used at the facility as a cover , material inside the cell, with appropriate approvais from the Iv�PCA and Dakota County. ', Minnesota Industrial Containment Facility 13425 Courthouse Boulevard • Rosemount, Minnssota 55Q68• 612/438-1500 •Fax 612/438-�549 _ . i f ! 1 � Amendment Request page two USPCI requests that the definition of non-hazardous industrial waste in the Rosemount Zoning ()rdinance be amended as fallows: Delete: Non-hazardous waste shall not include: ancinerator, resource recavery or power plant ash, or by-product from the processing or recycling of such ash;... Insert: Non-hazardous waste shali not include: ash generated by waste incinerators or waste resource reeovery facilities that burn municipal solid waste, or by-product from the processing or recycling of such ash;. . . We have enclosed a completed Zoning Ordinance Text Amendment Petition with the required fee, We will be contacting you to determixje what else needs to be completed in order to expedite this amendment. Please call if you have any questions regarding this request or if you have suggestions on how to proceed. Sincerely, Rex Kraft Facility Manager RKldd enciosures: Zoning Ordinance Test Amendment Petition and Application Fee cc: Bill Shea Ken Jackson Dt�n Chapde2aine Liane Hetherington-Ward Jim Gaughan Barry Schade Mike Mile� Lisa Freese , � � COAL ASH: ISSUES AND ANSWERS � By Frerlerick H. Gustin, P.E. Senior Project Engineer, Environmental Affairs KBK Enterprises, 1nc., Kennesaw, GA This paper will attempt to define the nature af ash that is produced from burning coaL What is ash? There are two by-praducts of combus#ion - ases and solids. Ash is the solid b - 9 Y product of cambustion. 1t is the non-combustible material that is contained in the fuel. The type oiash produced is a result of the type of fue/that is burned and of the type of boiler that is used to burn that fuel. Most electric utitities bum coal or oil to produce hea# inside a boiler, which in turn converts water to pressurized steam in tubes inside the boiler. The steam can either be used directly for heating buildings or in industrial processes, or else it is used to#urn a turbine coupled ta an eleetrieal generator. Other types af fuei that are commonly burned in the United States to produce steam and/ar electricity are natural gas and , municipaf salid waste (MSW)- How is ash produced? • , There are a nurnber of different types of boilers that are in use today to burn - '� coaL The most prevalent electric utility design is the type where finely pulverized coal, at about the consistency of face powder, is blown into the boiler and burned in a fire ball that is suspended in mid-air. This is called pulverized coal suspension firing. The othermajor boiler designs are the staker boiler and the c c/one boiler I�a. Y There are two types a€ ash that are praduced by burn�ng coal. Fly ash is fiir�e ,, particulate matter that is entrained in the fiue gases and cap#ured by a beghouse or electrostatic precipitator. Before air pollution contro( devices were placed into , common usage, this was the smoke ec>ming out of the stack. Bottom ash is '` caarser, mol#en, stag-like rna#erial that drops to the bottom of the boiler and is pulled ou# mechanically after being caofed. How much coal ash is praduced annuafiy? I The American CoalAsh As�oeiation estimates thaf in 1991, utilities in the U.S. bumed`approxima#ely 772,316,000 tons of c4aL Thfs r�sulted in the praduetion of 51,000,000 tans of fly ash, 13,300fl,000 tons of battorn ash, and fi,05Q,000 tons af taailer slag. Also produced were 18,100,000 tons of"FGD (f{ue gas desulfurization) material", pcimarily wet and dry scrubber residues I�I. �� . � � Coai ash is a very consistent mate�ial, both from a physical �nd chemical standpoint. Most electricaf utilities try to lock in long-term contracts for coai suppiies from a single mine at favarable prices. The quality of coal from a single seam or regian tends#o be eyctremely consistent day in and day out, year in and year out, making for eansistent ce►mbustion conditions inside the boiler. This is verified bythe purchaser on a regular basis through laboratory analysis of samples for their BTU, ash, moisture, and sulfur contents. These qualities certainly vary from region to region of the eountry, but as coal t�nds to be a relatively homogeneous material, eoal ash frorn a single source is also homogeneous. The following table shaws ranges of the major constituents of coal ash. RANGE OF MAJQR CONSTITUENTS BY CQAL TYPE t3��1 °To by weight of dry ash Bituminous Subbituminous Li nite Siiiea (Si02} 7.0-68 17-58 6.0-40 Alumina (AI�03) 4.0-39 4.0-39 4.Q-26 Ferric Oxide (Fe�03) 2.0-44 3.Q-19 1.0-34 Calcium Oxide (Ca�) 0.7-36 2.2-52 12,4-52 Sodium Oxide (Na0) 0.2-3.0 -- 0.2-28 Magnesium Oxide {Mg0) 0.1-4.Q 0.5-8.0 2.8-14 Potasium Oxide (K20) 0.2-4.0 -- 0.1-1.3 Titanium Dioxide (Ti�2) 0.5-4.0 0.6-2.0 0.0-0.8 Sulfur Trioxide (S03) 0.1-32 3.0-1 G 8,3-32 What are the environmental impacts of ash disposal? Environmental impact can occur via three mechanisrns: Gontaminat'ron of surface waters by runoff, confamination of groundwafer by leaching o# can#arr�inants, and surface ec�ntamination of surrounding areas by airborne fine par�iculate matter. Nowever, these are not issues in the disposal of coal ash due to the following reasons: • Runoff is contained within the disposal cell, preventing contamination of surface waters. , • Contaminants are prevented fr�m reaching the groundwater through#he use of synthetic and natural iiners, and collection and treatment of any leachate. • Fine particulates are prevented from becaming airborne by maintai�ing the ash in a wet condition, and the crust that forms when the ash has dried in place. . . . , ' Coal ash contains traee quanti#ies of most heavy metais in concentrations sirnilar to soils. in most cases, Ieachability af heavy metals approaches drinking water standards, However, routine testing of ash prior to acceptance#or disposat insures it's non-hazardous nature. Are there uses for coal ash? ' Coal ash has many uses. The most economicalty valuable is that of fly ash in portland cement cancrete and concrete praducts. More than 7.6 million tons of fly ash were soid in 1991 for this purpose. About one million torrs of bottom ash and boiler siag were used in concrete products, primarily concrete blocks. :Other uses include struct�rral filis, road bases, ice control (salt substitute), b{asting grit and roafing granufes, and waste stabilization and solidificat"ron to name bu# a few [21, 1Nhat are the standards and specifications for its use? Fly ash that is sold for use in concrete must meet rigid quality requirements for its chamical composition and physical characteristics. This is governed by a specification developed by the American Society for Testing and Ma#erials (ASTM) entitled "C-618, Standard�pecification for Fty Ash and Raw or Ca/cined Natura/Pvzzo/an fvr Use as a Mineral Admixture in Portland Cement Goncrete" �51.Specifications and standards are deveioped in order to pratect the customer, i and to provide a common ground for cammerce and science. References ,' [1]Babcock 8�Wilcox Company, Steamllts qeneration and use, Babcock&Wilcox, New York, NY, 39th edition, 1978. [2]The American Coal Ash Association, tnc, "1991 Coal Combustion By-Produc#-Production and Consump#ion", results af annuai wtility survey,ACAA, Washingtot�, DC. 1�92. . [3] Ray, S.S., and Parker, F.G., Characterization of Ash from Coal-Fired Power Plants, TVA, EPA-60Q/7-77-01 b, January, 1977. [4] O'Gorman, J. V., and Watker, P.L., Mineral Matter and Trace Elements in U.S. Coals,U.S. Department of fnteriorR&D Report No. 61, 1972. I, [5]American Society for Testing and Materials, 1991 Annual Book Qf ASTM Standards, Votume � 04.02, Philadelphia,PA, 1991. . . •-'_ "` Page 1 of 12 , , , Permit No. 2133 Spill Loeatian Gode - RM-00-t30-RM METROPOLITAN itiiASTE CONTR�L COMMISSI4N {MWCC) INBUSTRIAL DiSCHARGE PERMIT SPECIAL DISCHARGES Pursuant to the provisions o� Minnesota Statutes Chapter 473 �s amended, the Waste I3ischarge Rules £or the �Ietropolitan Disposal System (Minnesota Ru1es §� 5900 .1600 - 5900 . 7500 ) , and the MWCC Leachate and Contaminated Groundwater Progra,n, permissir�n is hereby granted to USPCI, Inc4rporated � One Commerce Green, Suite 500 515 W. Greens Road, Fioustan, TX 77067 for the discharge of _leachate __ into the Metropolitan Disposal System (MDS) at the Minnesota Zndustrial Containm�nt Facility, Gourthause Boulevard, R�semount MN 55068 This Industrial Discharge Permit is gr�nted in accordance with the application filed on Ju1y l , 1991 , and Fermit fees of $ 30.04 received. Discharge Limitations ; Monitoring and �eporting Requirements; Sgecial Canditions regarding connected and nanconnected sites; and Pezmit Conditions are contained in fc�ilowing sections of this Permit. Effective Date: September 4 , 1992 . Exniration Date: SePtember 30 , 1995 Issued by the Metropolitan Waste Cc�n�rol Cammissic�n DonaZd R. Mad�te . Director of Quality Gontrol Chief Admini.strator � � � � or duly authorized representative � � ate ' ' Page 2 of I2_, , Permit No. 2i33 ' Spill Locatian Code - RM-00�00-RM METROPOLITAN WASTE Ct}NTROL COMMISS�4N A. Discharqe Limitations • I 1. Loeal Limitations : Parameter MW'CC Local Limitation , Cadmium (Cd) 2,0 mg/1 � Chromium - total tCr) 8.0 mg/1 Copper (Cu) 6.� mg�l Cyanide - total (CN) 4.fl mg/1 _ L+�ad (Pb) . 1.0 mg/1 M r H 0 .1 m 2 e cur ( ) I Y 9 _ 9 �lickel (Ni ) 6.0 mgll , 2�nc tZn) ' 8.0 mg�l pii - maximum lfl .� pH uni Ls I pH - minimum 5.D pH units MWCC local limita�ions f�r metals and CN are the maximum for any opQratin3 day. pH limitations are instantaneous values . 2. Additional Limitationsz The following limits apply to le�chate and cdntaminated ground- water discharges: 'I Concentratian of any one toxic arganic parameter Z mg/1 Combined total toxi� arganics garameter eoncentrations 3 mg/1 I Total Hydrocarbons ( for pe�role�.m-related c3ischarges? 25 mg/1 i, Additional .Special Limits: Parameter N/R mg/1 • . • Page 3 of 12 t _ � , Permit No. 2133 Spill Location Code RM-40-0�-RM METROPC�LITAN W11STE CONT.Rt�L CUM.'+�lISSION 3 . Prohibited ntaste Dischar�es : Prohibited waste Discharg�s are deaeribed in S�ction 5900.4500 of the t�'aste Discharge RuZ�s for che MDS. I�cluded are sub- stances tr.at are flammable, ex�Zosive, obstructive to flow in a sewer, corrosive, toxic, poisonaus, radioactive or ha�ardous. In additian, substanees that are naxious or malodQrous which create a public nuisance or hazard ar� prohibited, as well as industrial pretreatment system sludge, wastewater with a temp- erature greater than 150°F, cooling water and other unpolluted watsr, and wastewater containing fat, wax, grease or oil that has the potential ta obstruct the flow in a sewer. Sp�ciric- aily prohibited is any wast� genezated outside of the seven county Metropolitan Area uniess a variance is granted 5y the Metropolitan Waste Control Commission. B. Monitorinq and Reporting Requirements 1. Sample Colleetian Representative wastewater samplets) shall be collected once �er month at the pc�int o£ discha�rge to the sanitary sewer, unlass specified differently in Sectian F. of this permit. 2 . Parameters Chemical analysis of the samples representing the waste discharge at �he specified site sha11 be performed for the . - Page 4 of 1� , Permit No. 2133 ' ' Spill Location Cade RM-00-00-RM METRQPOLITAN T�iASTE CONTROL COMMISSION following garameters: Se� Section F, Item �3 for samplinq frequency and Attachment A far the Parameter list. 3. Rzport? ng Reguirements a> Sehe�ule: The Permittee is required to submit Special Diseharge Reports to' the MWCC zour times per year aecording to the following schedule: ' ReAortinq Peri4d Reoort Due Date January 1. - March 31 April 3D , Apri1 i - June 30 July 3� Jul.y 1 - September 3U Qctober 30 j October 1 - December 31 January 30 I, Reports shall be �ubmitted each quarter until thi:s pezmi� 'I has been terminated, whether or not a discharge has occurzed during a given quarter. b) Re�oa:t Contents: _, A completed report eonsists of an MWCC Special Diseharge Report form and a capy of the laboratory data sheets €or , - all samples collected tor this di5charge during the ; reporting period, .The total discharge volume for the reporting period shal3 be regorted, as we17 as the , � ' Fage 5 of 12 , � r , germit No. 2133 Spill Location Code RM-Ufl--QO-RM METROPQLITAN WASTE C�NTRC?L COMMISSTON cumulative total volum� dischar�ed under this permit. � Other pertinent in�armation sha�.l alsa be included, such as op�rational proQlems and changes, etc. • The signature of the responsib2e �arty or a designated autharized � representative shall appear a� the bottom of the form. C. S�ecial Conditions for Discharqe Sites Not Connected to the Sa�itary Sewez " 1. Discharge LQcation Permitted discharges for �ites not connected to the sanitary ' sewer must be transported by an MWCC Pezmitted Liquid Waste Haulzr to the Third and Cammercial Disposal Site in St. Paul. 2. Load Charge Transparted discharges will be subject to a Laad Charge which includes a �volume charge and a strength charge tbased on analytical results) . The volume component is based on the volume rate that the MWCC charges each community serv�:d. The strength component is_.derived from the same equatian used to calculate Strength Charges for industrial users that are connected to the MDS, and is based on volum2, a Chemical Oxygen Demand cancentration in excess o€ 500 milligrams per liter (mgfl) and a Tatal Suspend�d Solids concen�.ration in excess of 250 mgjl. ' page 6 of I2 � , Permit No. 2133 � ' Spill Location Gode �•�RM-00-UD-RM METROPOLITAN WASTE CONTROL COMMISSIVN D. S ep cial Condition� for Discharqe Sites Connected to the Sanitary Sewer l. Connectian Approval Connections mado to local sewers or Commission interceptors shall re�uire approval fsom the aQpropriate authority prior . to connection. Bilting for sewer use shall also be arranged caith the community. 2. tlolum� Measurement . , The Permittee shaZl, install and m3intain an appropria�e ,, discharge metering device. 3 . Serviee Availability Charge tSAC) Effective January l , 1992, al.l Permittees shall be subject �.a ��I wastewater volume review for the purpose� of determining i£ additional Service Availability Charge tSAC? units are required. �,' Volume increases f�r which SAC was not paid caill be determined i for the 3 year permit duration period. Permittees will be notified of potential SAC liabilities one year prior to Qermit expiration. SAC due shall be obtained prior tv permit reissuanc< �� E. Generai Permit Cc�nditians 1. All discharges into the MDS shall be in accordance with app2ic- able provisions of the Waste Discharge Ru1es for� the MDS,' the MWCC Leachate and Cantaminated Groundwater Progra�, and this Permit. � ' . Page ? of 12 . r , , Permit No. 2133 Spill Location Code • RM-�0-00-RM ME'1'ROPOLITAN WASTE CQNTROL COMM�SSION 2 � The Permittee shall not knowingly mal:e any fa3se statem�nt, representation or certification in any record or report required to be submitted to the MWCC. 3 . This Permit shall not release the Permittee from any lia- bility, duty or penalty imoosed by Minnesota or Federal. statutes or regulations, or any loeal ordinances or regulations. 4. Tne Permittee shail take all reasonable preeautions to mini- mize all �ccidental discharges inc3uding s2ugs, spills and bypasses . In the event of any accidental discharges, spills or hypasses whose quaatity and nature might reasonably be judged to canstitute a hazard to the Commission's per�onnel and treatment faeilities or th� environm�nt, the Permittee sha11 ZMMEDZATELY notify the Industrial Waste Diviszon oi the MWCC at 772-7000 toffic� hours ) or 6�1-451.1 (non-o€fice h�urs} and report the site loeation, the spill location code, and othe.r pertinent infarmation. 5. The Permittee shall report any change in the �proposed discharge plan, ineluding changes in pretreatment system design or rate of discharge. The Permittee shall also notify the MWCC within 4$ houz�s if the sgstem is temporarily vr per- manently discontinued. • • Page 8 0€ 12 , , q . Permit l�o. 2133 � Spill Location Code RM-OD-4�-RM , N C MM SSIO N '� METROPOLITAI� WASTE Cfl TRL'L 4 I s b '� ti n A hall e 5. Any violatian of the limits lrsted in Sec o regor�ed to t'�e MtaCC immediate]:y. Failure to notigy the MWCC immediately may result in revocatian ' af this permit. � 7. 2he Permittee shail pay applicabZe 5trength Char�es , Add-on Service Charge� or Load Charges assessed by the Commission. 8 . The Permittee shali a11ow MWCC personnel to enter upon the Permittee's premises to inspec� the system and discharge point i; or sample the discharge in order to verify the reports ''� received and det�rmine comgiiance with the Waste Discharge I Rules for the MDS and this Permit in accordanc� with MR � �I 590iI . 31J0 . I'� _ � . - ' Page 9 of 12 , Permit No. 2133 . Spill Location "Cade . RM-00-00-�RM METRC3PQLITAN w'ASTE CONTRCIL COMMI�SION F. Specific Permit C�nditions . l. This gerinit covers the discharQe of nonhazardous industrial waste Iandfill leachate from the Minnesota Industrial Containment Faeility leachate col].ectionjstorage system: For the purposes of this germit, "leachate" shall also includ� ceantaminated starmwater runoff collected itom open cells and �tored in the ieachate collectionj�torage system. 2. The volume of leachate discharged sha1.1 not exceed 3�,000 gallons per day. Maximum rate of dis�harge shall be 62 gallons per minute. In the event of an em�rgency, USPCI, Ineorporated may contact the MWCC Industrial Waste Division to request approval to discharge valumes in excess of 30 ,E}00 gall.ons per day, however, the raLe of discharge �hal�l nat exeeed 62 gallons per minute. � 3 . A representative sam�aZe of the first batch of leachate shall be callected and ana3yzed for the parameters listed in Attaehment A. Results shall be submitted to the MWCC Industrial Waste Division priar tr, discharge. Thereafter, sampling shall be conducted on a monthl.y basis. Moze frequent sampling may be required if monitoring results show signifi- cant concentrations of regulated parame�er�. All parameter concentrations shall meet the limits listed on page 2 a� the permit. 4 . In the event that the parameter concentrations exceed the limits listed i�n pag� 2 , but are at ar below the limits for the Metropolitan Plant 43 mgjl per tc�xic param�ter and 10 mg/1 total toxic organies) the leachate may be hauled to the fihird and Commercial Disposal Site in St. Paul. Approval £or diseharge �o the Metropolitan Plant requires 24-hour advance notice to the MWCC Industrial Waste Division. 5. A11 leachate discharged at the Third and Commercial Disposal S�te must be transported by an MWCC permitted Waste Transport Hauler. All transport vehicles discharging at this site shall use a 4" or ].arger discharge :�ose. The MWCC reserves the right to restrict the discharge of ieachat�: to specific time periods in order to avaid system o�erloads, or treatment plant upsets or violations. 6. The Minnesata Industrial Containmen�. Faeility shall install and maintain a monitaring manhQle for the purpases of sampling and flow measuring leachateJwastewater discharges. The manhole shall be eguipped uitt} a f1Qw measuring device capable of curn�3lative volume measurement. :In addition, rec�rds of daily 3eachate discharge valumes shall be kept and submitted to the MWCC with eaeh quartezly self-monitoring report. , � , Page 1D of 12 " Permit No. 2133 Spill Location Code RM-OQ-Ofl-RM METRCPflLITAN WASTE C?NTROL COMMISSI4N F. Specific Permit Conditions 7, The MWCC reserves the right to impose lower limitatians than thase listed in Section A.2 if the discharge contributes to a ;reatment plant upset, a vioiation of a plant's NPDES permit, . or a violation of applicable sewage: sludge rules. Further, in the event of a treatment plant upset or violation, the MW�C may require the facility tc� temporarily suspend leachate discharge to the Rosemount plant, or to haul lPachate to the Third and Gomznezeial Disposal site. 8 . The laboratory reports for all wastewater monitoring canducted during each reprsrting period fat the point of discharge to the sanitary sewer) shall be submitted with the Special Discharge Repart for that period. Sample collection and analytical methods shall meet EPA protocol tCode af Federal Regulatians, Part Z36) . 9 . USPCI, Incorporated must notify the MWCC at least 94 days prior to commencement of initial diseharge. 10 . This discharge approval is not exclusive. The approval does nc�t release the Permittee €rom conditions set by the Minnesota Pallution Control Agency, Mir�nesota Department of Health, M�nnesota Department Qf Natural Resources, Dakota County or the City of Rosemount. i '� _-_ � � r� � _ . . .. � � �. • Page 1.1 of �_ . Permit Nv. 21�3 � - Spill Locati4n Code RM-00-00-RM METROPOLITAN WASTE CONTROL COMMISSZON ;' Attachment A. Sampling Parameters REVISED pH Total Chromium " Chemical Oxygen Demand Copper . Total Suspended Solids Cyanide S-Da� Biochemical Oxygen Demand Iron Ammonia Lead Nitrate, Nitrite Magnesium Ghlorides Manganese Sodiuzn Mercury Total Phosphorus Nickel Arsenic Potassium Cadmium Selenium Calcium zinc Pheno2 F�ash Point Sulfates Chloromethane • Trans-2, 3-Dichloropropene �I Bromomethane . Trichloroeth�ne I Vinyl Chloride Chloroethane _ �I' Methylene Chlaride Trichlorofluoramethane l, i-Dichloroethene l,l-Dicloroethane Trans-1,2-DichloroetheneC Chloroform 1,2-Dichioroethane 1, 2, 1-Trichloroethane Carbon Tetrachloride Bromadichloromethane 1, 2=DichZaropropane � Dibromachloromethane Cis-1, 3-Dichloropropene 1, 1, 2-Trichloroethane Bromoform 2-Chloroethylvinylether �� Tetrachloroethene 1, 1,2,2-Tetrachloroethane Chlorobenzene Acrolein Acrylonitrile Anthracene • I�, Benzene Acetone Toluene ' Tetrahydrofuran Ethyl benzene Ethyl ether ,' m-Xylenes _ Methyl ethyl ketone , para/or�ho-Xyle�es Methyl isobutyl ketone _:,- - � ;__ I�bpropanol_ . : �soprapyi ether - i . ;a - _ - _ __ - - = . � _�-�a.tr�sscsdim��l amine Si� �2=c3��:a���thyl.;e���r - - v � . �F3-Dichior:obenzene � 1, 4-D�chlarobenz�ne = =-- � 1, 2-Di�hlorobenzene Bis (a-chloro-Zsopropyl) ether � Hexachioroethane � � N-Nitrosodi-N-propylamine Nitrobenzene Isopharane' Bis (2-chlaroethoxy) methane 1,2, 4-Trichlorobenzene Naphthalene HexachZorobutadiene Hexachlarocyclopentadiene 2-Chloronaphthalene Dimethyl phthalate Acenaphthylene ' 2, &-Dinitrotoluene Acenaphthene ; 2 , 4-Dinitrotoluene 4-Chlorophenyl phenyl ether , _ . � � . • - , � , � � • Page 12 of 12 Permit No. 2133 SpiII Location.. Code RM--04-80-RM METROPOLITAN WASTE CONTROL CC?MMISSION � Attachment A. Sampling Parameters (continued) REVISED Diethyl phthalate Fluore�e 1, 2-Diphenylhydrazine N-Nitroso-dephenylamine . 4-Bromophenyl phenyl ether Hexachloroben�ene Phenanthrene Fluaranthene Di-N-butyl-phthalate Di-N-octyi-phthalate 2-Nitrophenol 2-Chloraphenol 2, 4-Dichlorophenol 2,4-Dimethyiphenol 2, 4, 6-Trichlorophenol 4-Chlorr�-3-Methylphenol 4-Nitrophenol 2,4--Dinitrophenol Fentachlorophenol 2-Methy1-4, 6-Dinitrophenol . , •� . - Page 11 of 12 , , � Permit No. 2133 . Spill Location Code RM-00-00-RM METROPOLITAN WASTE C�NTRJL COMMISSION Attachment A. Sampling Parametexs pH Total Chromium I Chemical c�xygen t3emand Copper i Total Suspended Solids Cyanide 5-Day Biochemical Oxygen Demand Iron . Ammonia Lead Nitrate, Nitrite Magnesium � Chlarides :�anganese Soaium Sulfates :�ercury Total Phosphorus Nickel Arseni� Potassium Cadmium �elenium Calcium Zi:nc Phenol F1ash Point Chloromethane Trans-1,3-Dichloropropene Bromomethane Trichloroethene _ Vinyl Chloride Chloroethane Methylene Chloride Trichlorofluoromethane ' 1,1-Dichloroethene , l,l-Dicloroethane �I Trans-1,2-Dichloroethene ChlorQform 1,2-Diehloroethane l,l,l-Trichloroethane Carban Tetrachloride Bromodichloromethane �, 1,2-Dichloropropane Dibromochloromethane ' , Gis-1,3-Dichloropropene 1,Z,2-Trichloraethane ' Bromaform 2-Chloroethylvinylether Tetrachloroethene 1,1,2;2-�Tetrachloroethane �', Ch�.orobenzene Acrolein ' Acrylonitrile Anthracene' I Benzene Acetane ' ', Toluene Tetrahydrofuran Ethyl benzene Ethyl ether ', m-Xylenes Methyl ethyl ketone I paraJortho-Xylenes Methyl isobutyl ketone '� Is�propanol Isopropyl ether I, N-Nitrosodimethyl arnine Bis t2-chloroethyl)ether ', 1,3-Diehlorobenzene. 1,4-Dichlorobenzefle ', 1,2-Dichlorobenzene Bis t2-chlorQ-ZsaproQyl) ether Hexachioroet'hane iv-Nitrosodi-N-propylamine Nitrobenzene Isopharone Bis t2-chlor�ethoxy) methane 1,Z,4-Trichiarabenzene Naghthalene Eiexachlorobutadiene A�xachlorocyclopentadiene 2'-Chioronaphthalene I Dimethyl phthalate� AcenaQhthylene 2,6-.Di.nitrotoluene Acenaphthene 2,4-Dinitrotoluene 4--Chlorophenyl pheny�, ether Diethyl phthalate , F].uorene : ' 1,2-Diphenylhydrazine N-NitrQso-dephenylamine 4-Bromophenyl phenyl ether Hexachl:orobenzene Phenanthrene F1:uoranthene Di-N-butyl-phthaZate Di-N-c�ctyl-phthaiate . • - _ � . Page 12 of I2 , , , � � Permit Na. 2133 Spill Locati.on Code RM-00-00-RM METROPOLITAN WASTE CONTROL COMMISSZON Attachment A. Samgling Parameters (continued) . � 2-Nitrophenol 2-Chlorophenal 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4, 6-Trichlorophenal �4-Chloro-3-Methylghenol 4-Nitrc�phenol 2,4-Dinitrophenoi Pentachlorophenol 2-Methyl-4,6-Dinitrophenol . , t �', 1 FLY ASH USED AS A SArIITARY LANDFILL COVER ' Fly ash and bottom ash have been successfully used ir� sanitary 'i landfill operations as a cover and compaction media. Research has demonstrated that fly ash is particularly effective in I� accelerating decomposition of household refuse and aid's in the compaction of the refuse which would extend the exp�cted life of such landfills . The ash cou7.d become a valuable asset for landfill a.perators in areas where cover material is in short supply or sin�ply not available. ' .• SQme advantages ta be gained from using ash in these areas arer 1 . Percolatian thraugh fi11 is r�au��a due ta compact- ability of fly ash thus reducing leacheate to ground , and surface waters; .. 2 . Ash is more inert than other readily availab3,e mate- rials having been fired thraugh a temperature of 1Q�0°F; � 3 . Moisture content of f�y ash can be varied and controlled � to suit operator' s needs ; 4 . Ash is available 365 days a year while, because of ' freezing oR wet conditions , soil or other cover mate- �'� rials may be unusable. References : • , 1) F1y Ash Pioneers , a Reclama�ion Eeonamy as Energy/Resource Challenges Confront Engineering Cammunity � Professional Engineer - �ul.y 1974 , Pages 18-22 2) F1y Ash Utilization - A Summaxy of Applieations and Technology U.S . Bur�au oE Mines Tnformation Circular 8483 1970 3) Fly Ash - Joining The Ranks of Natural Resources by John H . Faber, PE , I Resource Recovery - September/October 1974 �, ALH :jd 3-7-80 rn . � , , . BOTTQI+i ASH US ED AS A F I LTER i�iATER I AL Bottom ash can be used as a filter material . The uniformity of the mate.rial poses no pxoblem wi.th obtaining consistent permeability constants . The permeability i� equivalent to that of clean sand. Bottom ash has been utiiited as underdrains in highwa}�s , drainage material behind retaining wal3.s and as chimney and abutment drains in dams . Placement of the bottom ash can be accomplished by cqnventional methods currently used fQr clean granular mat,,erials . Referen�es : 1� Bottom As}l� and Boiler Slag ,by. L . K:. t�ioulton, Civil � Engineering � Professor, i�lest Virginia �Jniversity. Proceedin�s: 3rd International Ash Utiiization 5ymposium Z) American Electric Power Serviee Corporation Ash Utilization and Peseareh Section J� ' J 1 l BOTTO�f ASH USED AS AN AGGREGATE TN COLD-1�tIX` ASPl�:'1LT OR BITUAiINOUS-STABILIZED BASE COURSE Bottam ash possesses valuable engineering properties . For the I mt�st part, it is an angular, well-graded material rangins in size from +3/8 to - 200 mesh . It is sound and durab'le and has a gaod affznity for emulsified asphalt . Bottam asl� has been utilized as a base cou.rse aggregate in the repaving of 40 to 45 miles of rural secondary roads in 1�'est Virginia . The material was cold- lai.d wi��th a paver or spreader box �oit}� adequate compaction achieved from several passes with a pneumatic roller, followed by a ste�l -drum roller, This material has proven to be an effective base course . . , An important advantage of cold-mix as halt is its sim lic' t T� , p � y • I'i The ash zs loaded into a hopper af a partable pugmill , mixed with an emulsified asphalt, and loaded directly intc� trucks � or stockpiled for future :use - such as patching . Simplicity of production and a large local ash su 1 account for the I low cost of Lhe mix . PP Y References : 1) Asl�phalt - tiVest Virginia Turns IVaste Niaterial Into Useful Aggregates , Asphalt Institute Publication 2) Bottom �Ash and Boiler Slag by L . K: Moultom, Professor of Civil Engineering , �Vest Virginia University ' � , Procee . a ings : 3rd International Ash UtilizatiQn S m osium Y P I /� , � � , . . FLY ASH AS A FILTRATION MEDIUM FOR SN5ULATING OILS USED BY UTILTTIES The similarities in chemical. constituency of fly ash when compared to Fuller' s earth has lead to the testing of f1y ash as a fil.tration medium for cle�ning used insulating oil. Fuller' s earth is the commercial term applied to the natural bleach- . ing elays originating in the southeas�ern United States (principal.ly Fla. and Ga.�) . These clays are either granulated ar pulverized and are used for filteration by. either the percolation or contacting process. The following table is a comparison af the typical chemical analyses of fIy ash to Fu11er's earth. The analyses show that the chemical compositi.on of the fly ash is very close tc� that of the Fuller' s earth �xcept for the higher organic mafiter present: in the Fuller' s earth. • Chemical Analysis Fuller' s Earth* FI.y Ash* Ferric Oxide 3-$ 3-18 • Silicon Dioxide 50-54 45-60 Titanium 'Oxide . 5-1. 2 1.fl-2, 0 Aluminum Oxide 9-18 24-32 Phosphoric Anhydride . 1-1. 2 . 1-1. 0 . Magnesium Oxide 3-9 .5-1. 5 Calcium Oxide 1. 3-3 . 5-4 . 0 Sodium Qxide . Q1-. 05 . 5-4_. a Potassium Oxide . 5-1 . 0 � . 5-1 . 5 Sulfer Trioxide . 41-. 05 . i-2 . 8 Trace Elements . 05-. 15 . 01-. fl5 Loss of Ignifiion 9-16 1-12 . *Analysis based on percentage by weight I€ viewed microscopi.cally the cenospheres of the fly ash Wflu�a ai�- ferentiate these igneous particles from the Fuller' s earth particles which are more irregularl.y shaped and flake-like particles. Both of fly ash and Fuller's earth vary in their hetearogenity depending upon either the coal which is fired €�r the mined source area of the Fuller' s earth. Tests have been done tio determine the effectiveness of fly ash as a filtratian medium far insu:lating oil and the results have been en- couraging. A11 the ph�sical and el�ectricial propterties of the oil were improved . � � . i � � ���,�. Fly Ash As a Filtration Medium For Insulating Oils Used By Utilities - 2 - Current research is being done to determine a practical method to I' use fly ash as a filtration medium on a larger scale. References : ' 1. Fly Ash as a Reclamation Agent for Used Ir�sulating Oils by John Tamshaw and Joseph Padula Public Serviee Electric and Gas Company `� Newark, New Jersey Presented at the Dobie Cli�nts Meeting, April 1976 2. Adsorption by C. L. Mantell, Ph.D . ' • Second Edition - McGraw Hi11 Book Company, Inc. , 1951 ALHst Y 6/zsJ79 � ,� � . . � , ` , . May 17, 197�J Fly Ash As An A��re�;ate For The Stabilzzation of Hi�hway Suberades. The Qutstandsng property which makes fly ash a viable engineerin�; material is its po;zolanic nature, The poxzolanic reactic�n between fly ash and lzne can result in a material of substantial strength. Natural pc�zzolans, such as volcanic ash, have been hi�hly regarded con�truction, materia2s since ancient times, This property of fly ash has been employed in various phases of hi�h�ay construction in this country, and abroad. F2y ash stabi2ized with lime and/or cement has been u`sed in base and subbase courses for roadway pavements. In additian tn the po2zolanic nature of the fly ash, the relatively light unit wei�ht af fiy ash has made it a.particularly suitable fill. material aver areas of weak sub�rade where heavier materials could_ cause excessive settlement or f�ilure in ' the weak soils. In addition, any self-hardenin� properties which a fly ash may possess tend to increase the fly ash's shear strength wzth tine, rendering the fly ash a very stable material capable, in many cases, of sustaining substan�ial loads. References: 1. American Society for Testing and idaterials, "Standard Speci�ication for F1y Ash and Other Pozzolans for Use with Lime - Procedure . C 593-69," 1975 Annua2 Book of ASTtd Standards, Vol. 13� 1975. 2. Barber� E. G., "The Utilization of Pulveriaed Fue1 Ash,'' Journal of the Institute af Fuels, Vol. 43, No. 3�$� January, 1970 pp• 4-9• 3. Holli�, B. G. and Fawc�tt, N. D. , "Laboratory Inves�igation of the Usc of ;•tixtures of Lime and Pulvcrized Fuel Ash for Soil Stabilixatiart," Roads and Road Construction, Vol. 44, No. 51�� Janvary 1966, pp 3-�i, and tdo. 518, February 1966,-PP. 34-39. � 4. ;•tcyers, Jaaes F. ; Fiehumani, Rar�on; and Kapples, E3ernadette S. "I'ly Ash" a }ti�haa;� Gons�ruction Fdat�rfal U, 5. Departmez� af Transp�ortatian, June 1976. , dch . • ' � ,. - . � THE USE OF FLY ASH AS A MINERAL RESOURCE �ly ash shows potential as a mineral resource specifically for �II ;he recovery of alumina and iron. ^he range of constitutents far power plant fly ash is as follows : Constituent Percent Silicon dioxide �5 - �� Aluminum �oxide 24• - 32 Ferric oxide 3 - 18 Calcium oxide �•'�. '" � Sulfur trioxide 0. 1' - 2• 8 Patassium oxide 0. S - 1. 5 Titanium oxide • - .1. 4 � 2 . 0 . Magnesium oxide , 0. 5 - 1 . 5 ° Sodium oxide 0 . 5 - 1. 5 • Phosphorus pentoxide 0 . 1 - Q . � , Trace elements O. Ol - 0.05 The technology is -available to extract the alumina and iron from . the fly ash. At present mast of the alumina used is extracted from bauxite which has a 40-65$ alumina content campared with the 24-32$ alumina content of fly ash. The ferrie oxide content of eommercial grade iron ore' is 62-70� while the ferric oxide of fly ash is 3-18�. The alumina and ferric oxide content of fly .ash is substantially ' als. However c mmerciall used raw m ater�. lower than that of the o Y the advantage of using fly ash as a raw material. for mi,neral rec- lamation is that at present much of the bauxite used for aluma.num is impor�ed and is subjected to forei.gn controi. Iron ore has to is readil available within the United � be mined while fly ash y States, Research is being done to determine the most economi.cal methods , f mineral exta:action and ilot plants have been set up and are o P . � being evalua�ed. References : 1. Pawer Plant Rsh: A New Minerai Resource by R. E. Morrison i' Rsh Utilixation Proceec�ings: Fourth Xnternational Ash Utilization Symposiumf I� March 1976 rom Power Plant F'ly A sh i.n I on and Alumina Extraction f . 2. r Poland by Zyg.£ryd Novak Ash Utilization Third Interna�ional Ash Utiliza�ion Symposium, 1973 � . � . � 4 � � � � � � � � . FLY ASEi USED I�! THE A�lELIORATI4N Ot= SOILS It is not difficult to think of �lY as� erialslsuch�as soil ,tcla�` ing properties since ash consists of mat and shale , With the exception of nitrogen, fly asl� contains most elements required for plant growth . On the basis o£ this elemental com- posiLion, the by-praduct is a suitable s�uo��acidicTsoilsPandt nutrients . Fly ash may also raise the p increase tlie �aater retention capabilities of• soil not����aPable of retaining sufficient moisture to sustain pl,ant s These beneficial effects of f�y ash applications on the soil and plant growth are expected to encourage £uture utilizati4n of -fly . ash in agricultural soils . � . Refexences ; - 1) Availability of Plant Nutrients iFQ�1����ni�CalpTnstitute�ns , Department af Agronomy , Vir�inia y and State University C. p. Plank and D. 2) Amelioration of Soils wigh F1yyAsvibYini.a Polytechnical Mart�ns , Department o£ A ranom , 8 Institute and State University ,.. „ ,� , Ba �r Engineering Company , &300 Norman Center Drive Minnea�lis,MN 55437•i026 �I;. Phone: (612)832•26U0 Fax: (612)835-0186 April 39, T993 Ms. Lisa Freese Director of Planning City of Rosemount 2875 145th Street West Rosemount, MN 55068 Rec U3PCI Request to Accept Coal Ash Dear Ms. Freese: I have reviewed your FAX transmittal of April 14, 1993 from the Metropolitan Waste Control Commission (MWCC) . The MWGG has influent and effluent eompliance requirements for their wastewater treatment facilities and as such, has a thorough understanding of the impaets various influent waste streams may have on effluent quality. Therefore, it is appropriate for the MWCG to deterrnine what additional constituents, if any, should be evaluated during testing of leachate from USPCI's MICF. 5ince the MWCC has identified no additional leachate testing requirements, it would appear as stated in their I' letter, that leachate from the MICF will be aaceptable for diseharge to the MWCC treatment facilitzes. Given the requirement that leachate from the MIGF be temporarily stored � pending results of leachate testing, it is my belief that this provides adequate opportunity for evaluating whether or not to discharge Zeachate. As indiaated in zny letter dated Apri1 8, 1993, dispo$al af coal ash at the MIGF appears to ' pose little risk to the environment pravided the waste acceptance plan and facility operations plan is properly implemented. Therefore, I recommend the j �a.ty �+f Rasem�unt modify the zoning ordinance as necessary to allaw disposal of ' coal ash at USPCI`s MICF. If you have any questions regarding recommendatians presented herein, � please feel free to ca11 me at 832-2871. 5incereiy, II �j '' A ." I �,.,v-r �i/! ' �,T-�iG�.��_ Thomas J': Radue, P.E. TJRltmk cc: Bill Lauer, Dakota County 23\19\260\LF9.LTR GPR-14-1593 0^0�52 FROM MWCC INDUST�IAL WASTE DIV TO 9��35��3 P.G2 �� . ������' � Metro�olitan.VVasxe CQntroi �amx�ai�ssiot� Mears Park Ccntrc,230 Easi Fifth Strcet, St. Paut, Minnesata 55lOi-t63� � b12 222-8423 , Agri1 '14, Z993 ' M�. Lisa Freese Di�ector es� Planning � city of 12osemaunt , P.O. Bpx 510 ' 2875 - 145th Stre�t W�st , �tosempun�, Minnesota 5506a-4514 RE: USPCI Goal Ash Aear Ms. Fr�es�.: � Sas�d on the i�forzaation prvvided by Barr Engine�ring and a r�vi�w , o� �literature data c�n coa3. ash, it is our feeling that the � acc�ptance af c�al ash at th� Minnesota Ir�dustria2 Corttainment Faci3ity will not p��sent a problem for leachate d�spt�sa3 into the MWCC sys�em. Th� MWCC permit issued ta USPCI r�quires that �very ta�nk b� sampled and th� data be apprav�d pra.ar ta any discharq� ta the Rosemount plant. I� any �cons�itu�nt excec�ds p�rma.t limi�s, but would m�et the limits for the M�tropolitan plar►t, they have th� vption of hauling it to the Third and Commer�i�l d�spdsal sit� in St. Paul. � Zf concentr�tior�� exceed th� limits sat tor the Metrapolitan p].ant, USPC�. wauld b� required to treat the waste prit�r �o dischar�e c�r , find an alternative dispasal m�thad. We hel:ieve this procedur� provides adequate safeguards for �ur sys�em. In add�itian to �he permit sampl.inc� requir�ment�, the MWCG R & D , divisit�n has agreed to perform taxicity testing once wastew�ter containing eoal ash Ieachate has been generated. IF you have any questions reqarding the USPCI permit, pieas� call me at 772-7049. Resp�ct�ully, i ��,^�w,,, . � rur t , Lyrin H�lly St�a�Ef Engineer � �ndustrial Waste Divisi�n , cc: L�o Herrn��, MWCC Dc�ug Warner, MW�� ; 8i11 Lau�r, Dako�a eoun�y , � . � � : . • ' � : I �4u���PPo�u�ttYiAttlrma�rte M:Gon�mpicyer ' � � t�t ,� ' TOTA� P.0'? � � ��� r, ' i ' �`;� Metxopolitan Waste Control �ommission Mears Park Centre, 230 East Fifth Street, St. Paul, Minnesota 55101-t633 612 222-$423 I May 10, 1993 Ms. Lisa Freese Director of Planning . City of Rosemount P.O. Box 510 2875 - 145th Street West Rosemount, Minnesota 55068-0510 RE: MICF Coal Ash Dear Ms. Freese: Attached you wi11 find a xeport from LeeAnn Johnson of MWCC's R & '� D division concerning fly ash leacha�e/Rosemaunt WWTP toxicity testing. This pro�ect` was conducted in respanse to your concerns i regarding the acceptance of fly ash at the Minnesota Industrial I Containment, Facility (MICF) in Rosemount. Ms. Johnson's conclusions confirm our initial belief that acceptance of coa3 ash � at the MICF will not present a problam with leachate disposal into 'i the MWCC system. According to Rick Potrament of MICF they wi�.l not be accepting coal fly ash for waste disposal per se. They intend to use it as a ' stabilizer on their internal roadways and, maybe in the <future, offer a.t to their eustomers as a salidificatior� agent fflr wastes which may contain some free liquids. In that case, the portion of ` leachate fram f].y ash would be much less than what was estimated for the toxicity tests. If you have any questions regarding the attached report, or any other concerns about the MICF permit or discharge, please call me , at 7'72-7009. SincerelY, �I ����'7'� '� ; ' �...��.�,�-, L�nn Holly Staff Engineer Industrial Waste .Division !, cc: Leo Hermes, MWCC Doug Warner, MWCC - I Jim Brown, MWCC Bil1 Lauer, Dakota County Equal OpportunitylAffirmative Action Empioyer ' �i ,-s+�.'� t'U . r ' � 1Vletrop►olitan Wa�te Control Camr�issio� 4ffice Memorandum To; Lynn Ho(fy �, Date: May 5, 1993 � From: LeeAnn Johnsan �' Subject: K�ng's Leachate Toxicity Testing INTRODUCTiON This memo wilC summarize tests conducted by the Research and Deve(opment Division to examine the toxicity of King's fly ash leacfiate. It is anticipated �thai a similar leachate will be dischacged to the Rosemount wastewater treatment plant if fly ash is aecepted at the industrial landfill in Rosemount: The testing consisted of two parts: [�l Determination of Rosemount plant axygen uptake rates in control systems and in systems amended with various concentrations af fly ash leachate. These tests were performed using a Bioscience Management tnc. B1-10Q0 electrolytic respirometer. [2] Measurernent of MicrotoxTM toxieity c�# the fly ash leachate. RESPIRUMETRY The Bioseience Management Bt-1Q00 electrolytic respirometer measures axygen consumption by micraorganisms metabolizing organic and inarg�nic P substrates in wastewatec. The presence of tox're substances in toxic amounts inhibits the metaholic activity of the microbial poputation, and causes a decrease in oxygen uptake rates and/or a decrease in the total amount of oxygen consumed over the course of the test. In the standard protocol, biamass and wastewater from the affected trea#ment plant�are used in the test system. Thts mxxture is amended with concentrations of an industriat discharge {or chemicatf representing realistic to warst case conditions #or the treatment plant. Oxygen consumption in the test ` reactors are compared with oxygen consurnption in cantrol reactors which do noi rece,ive the industria! waste. A schematic ot a Bf-1 Q00 standard reactor is shown in Appendix B alang - wifih art explanation of its operating princ'ipl�s. The BI-1404 system wili . a+ecommaciate $ t�ne-liter reactors, and includes temperature control and stirring capabilities. The er�tire system is cornputer contralled. , ` - I r� ' a PRINCIPLES OF TME MICROT�X TEST The Microtox toxieity test is a commerciatiy-availabte toxicity test system �' <manufactured and distributed by Microbics Corporation, Inc. Like other bioassay systems, it chatlenges a iiving organism with a test sampie and measures a response frorn the organisrn. The test arganism (also called the "reagent"1 is the � luminescent bacterium, Photobacterium phosphoreum, a marine isotate which II produces light as part of its normal metabolism. The iight output of the reagent is measured before and after the reagent is exposed to the test sample under controlled conditions of time and temperatur�. When the reagent's metabol'rsm is inhibited by the presence of toxic substances, its tight output is reduced. In the standard Microtox test a range of sample concentrations are examined along with a non-toxic positive reagent control. The data is used to construct a dose-response curve from v�rhich an EC50 vatue is caiculated. The EC50 is the ;' effect�ve concentration at which there is a 5t}°!o reduction in light output due to !I toxicity. EC50 values can be compared in a relative way: A sample with a Iow EC50 ', value is more toxic than a sample with a high EC� value. in ef#ect, a lower ', concentratian of a more toxic sample will cause the same tesponse (50% light '� {ass) as a higher concentration of a Iess taxic sample. I EXPERtMENTAL I Respirometr� I Samples from the first celi of the Rosemount aerated lagoon and of King's fiy ash leachate were provided by the Industrial Waste Division on Apri1 23. The samples were used in the respirometer test as provided. Duplicate reactars df each of the fotlowing treatments were prepared: , . Treatment Reactor contents Controi 950 m1 Rosemount' + 50 ml distilied water 1 % leachate 950 ml Rosemount + 10 ml le�chate + 40 ml distitled water 2%0 leachate 950 m{ Rosernount + 20 ml: leachate + 3C1 ml distilled water 5°l0 leachate 950 ml Rosemount + 5� ml leachate - ,' The respirometer ran for one week at 15°C. : _ ',; . Microtox Analvsis . . - A sample of King`s_fty ash leachate was analyzed far Mierotax toxicit�r. Th� . - - - sampie was stored in a refrigeratQr in glass screw-c�p #est tubes couered with `: _ �- ,�„_Parafilm�` unti! analyzed. Microtox analysis was cor�du�tetl on the s�mpl� usin��_ :-._� ,�.� � : :: : _ -- -. : - - : _ - _ .�� - :� - - - __ . _ - - �- '"Rosemount" rneans sample colleeted frarn the first ce1( of the Rosemount. wastewater treatm�nt plant. 2 _ . a. y . . . . . . . . . � � r� . � . . � . . � * standard procedures (Appendix A}. The Microtox data w�s reduced using Microtox flata Reduction So#tware Version 6.0. A description of da�a reduction methods is included in Appendix A. RESULTS AND QISCUSSfON Res�irometry . The results of the respirometer test are summarized in the attached figure. The accumulated oxygen demand graph shows the totai amount of oxygen utilized by the biomass in each respirometer reactor over the course of the experiment. Eact� piot represents the average resuits Qf duplicate reactors except for the "1 °70" plat where data from only one reactor is presented. The stir bar in the secand "1 °lo" reactor uncoupied fior several fiours making these results �nvalid. As we have already discussed, the first day's data could nat be used because the respirometer had been improperty programmed. The problem was corrected on the second day of the incubation, and the data fnr the remainder of the test was collected correctly. The data presented in the accumulated axygen demand figure was "zeroed" on day two to bring all reactors to the same starting point, 1 am confident that the results we obtained far the remainder of the test are valid and repr�sent the microbia! activity in the reactors. Sased on the results ofi this testing, there was no apparent oxygen uptake inhibition at any concentration af fly ash leachate examined. You have indicated that the indust�ial landfil+ is atfowed to discharge a maximum o# 30,Q00 galians of leachate per day, or approximately five percent of the total flow to the Rasemount plant. The highest concentration examined here, five percent leachate, would represent a worst case scenario for f!y ash in which all of the discharged Jeachate consisted only of fly ask� ieachate. in fact, axygen uptak� was slightly higher in the reactors receiving fly ash than in the control reactvrs. Microtox � The resul#s o# the Microtox analysis and data reduction for King`s fly a�h leachate are attached. The tesfi did not provide a sufficient r�ur�ber of vatid data points to calcutate an EG50 value for the sample, h�wever, a review of the.gamma vatues generated during the test indicates that the sample is not toxic. As explained in Appendix A, the.�amma value is the ratia o# light remaining to iight fost due ta toxic exposure. A smali gamma ualue, i.e, cic�se ta zero, indicates low toxicity. For the leachate sample the gamma value at the highest cancentfation was negative at both time points indicating a small stimulatory ef#ect. A}though we �7ave not analyzed a Rosemount plant influent s�mple for Microtox toxicity, we have anafyzed hundreds af plant influent samp(es from other treatment plants in 3 , ` <. . ' the MWCC system including Metro, Seneca, Hastings, Anoka, and Stiliwater. These samples typically have�a Microtox EC50 value in the range of 2-50°l0, and we have atways detected toxicity in these samples. My conclusion based on these comparisons is that the King's leachate is actually less toxic than typical municipat ' wastewater. . ' � CONCLUSIONS Based on the results of xhese respirometer and Microto� tests, it does not appear that King's fly ash leachate is particularly toxic either in terms of Mierotc�x toxicity or inhibition of wastew�ier microorganisms. As such it should not cause process interferences in the Rosemount t��atment plant, Since the feachate tested here is not the same Ieachate that would be discharged frc�m the industrial landfill in F�asemouni, it may be prudent to conduct further testing if/when the (andfill accepts fly ash or if the treatment plant develops problems after the fJy ash is � accepted. cc: Bob Polta --� File attachments 4 , � � � , ° F�osemount Plant Toxicit Test . Y King's Fiy Ash Leachate 30 .... � �- � Control � 25 �- ---+--- c 1°/a � 20 -�— a 2%° ai � m 15 " ' 5°!0 x . a � 10 . .� c� � � � 5 U U Q � Q �20 -_ ,.4Q 60 80 100 120 140 160 180 :. _ Time (hours) . . � �,��.���,. . . . . . . �i I ��. MICROTOX DATA REPORT FILE NAME: LEACHATE.KS TEST DATE: TEST TIME: Sample Description: KING'S LEACHATE, RECEIVED 4/23/93, ANALY2ED 4/27/93 Procedure: BASIC Osmotic Adjustment; MOAS Initial Concentration : 45.5 $ Dilution Factor : 2 Test Time: 5 minutes Concentraticin 'Units: $ .NUMBER I0/IT CONC. GAMMA 1 87j 66 5:6875 0.10176 2 87/ 64 11.3'750 O.I36T9# 3 87j 66 22.7500 0.10176� 4 83/ ?0 45.5000 -0.00896* CONTROL IT/I0 = 312f134 BLANK RATI4 = 0.8358 _ * Invalid gammas I' MIGROTOX DATA REPORT FILE NAME: ZEACKATE.K15 TEST DATE: I TEST TIME: Sample Description: . KING'S LEACHATE, REGEIVED 4J23/93, ANALYZED 4/27/93 Procedure: BASIC Osmotic Ad'ustment: MOAS � II' Initial Concentration : 45.5 � Dilution Factor : 2 Test Time: 15 minutes Concentration Units: � ' NUMBER IO/IT CONC. GAMMA ^---- ---/--- ---------� -------=- I 1. 87 60 5.6$75 O.I1455 2 $7f 59 12.3750 0.13344�` 3 87/ 63 22.'I5Q0 0.0624$�` 4 $3/ 66 45.5000 -0.03336* C4NTRC)L IT/IO = 103J134 BLANY: RAxIO = 0.76$? �I' * �nvalid gammas ' 4 t , ' � APPENQIX A MICROTOX STANDARD TEST Materials and suppfies Microtox toxicity analyzer [Fig. A-1] Microtox reagent - the test organism, a marine bacterium, Photobacterium phosphoreum. Microtox reconstitution solution - distilled water used tt� rehydrate the freeze-dried reagent. � Microtox osmatic adjustirrg solution (MOAS� - 22% NaC1, used to adjust the salinity of (non-marine) samples before dilution. Microt4x diluent - 2%� NaCI, used to prepare serial dilutions of the sample. Cuvettes - fiat-bottomed test tubes tsheli vialsf used to contain samptes, controls and reagent during testing. Anatyzer preparation [Fig. A-2(a?l 'I . 1 .0 ml of reconstitution solution was added to a euvette in the 5°C precooling weli. Z. 1,0 mt o# diluent was added to cuvettes in A1 through A4. 3. 500 �ri of diluent was added to cuvettes in B1 through B5. Sample preparation [Fig. A-Z(b)] -, 1. 2.5 ml of sample was added to a cuvette in A5, and the sample was osmoticaliy adjusted by adding 250 ,ul of MOAS to tfie cuvette and mixing. 2. Two-fold serial dilutions of the sarnple were prepared as follows: a, 1 .0 ml w�s transferred frorn A5 to A4, and A4 mixed. b. 1 .0 ml was transferred from A4 ta A3, and A3 mixed. c. 1,4 m1 w�s transferred fram A3 to A2, and A2 mixed. d. No sample was added to A1 whieh was used as the control (blank?. 3. Dilutions were alfowed to equilibrate to 15°C for 5 minutes. Reagent preparation [Fig. A-2(c)� 1 . A vial of Microtox reagent waS reconstitu�ed by rapidly adding the reconstitution solution from the precooling well to a fresh vial o# freeze-dried reagent; mixing thoroughly, and transferring the mixture back to the cuvette in the precoc�ling well. 2. 1� ,ul of the reconstituted reagent was transferred to B1 through B5, and mixed. 3, The reagent suspensions in B1 to B5 were allowed to stabilize fQr 15 minutes prior to t�se, ,A-1 . � 1 . ,� � i - Assay procedure [Fig. A-2(d)l ,' 1 . To measure lo Hght levels: ta) c�vette B� Cblank� was placed into the turret ; . weli, fhe turret was closed, the light leve! was set to approximatety 090, and the.value recorded; (bI the remaining cuvettes, B2 to B5, were similariy cycied through the turret w�li to obtain In light levels without making any adjustments to the analyzer. 2. Immediatefy foliowing the initial readings, the foilowing 500 �1 transfers � were rnade using the pipettor to m�x the samples: A1 to B1, A2 to 82, A3 to B3, A4 to B4, A5 to B5. �i 3. Five and fifteen minutes after the last lo light levei was taksn, the cuvettes were again cycied through the turret well to obtain 15 and t15 Iight levels. 4. Atl tight readings were either recorded on a strip chart.recorder or read directly off the analyzer digital display, Numbers and sample in#ormation were recorded on a standard worksheet. �I � ' � �! �� ii �� , ? ' + ' I � �■�� � •��������'��/�����"���� �a1 � i , ; , ; � � �� �..�. � !�" ��' 1 7 3 ♦ 5 . ' LJ �t�.�� � � �� �. � . � � � I cr�woi�no w��-'--�r.• " � � � � � �c-........ 8 � � 0 � � . � , I I�I � � � + � � � • � � � � L� ii � � �s.���a�� a s�,e..,,,�,< i � Q �nc.veeo-• �. . .� . � . � . � � . . . Q • 'N11 BIOCk . � ) � f. .. p II�,�. ° r_�i�r�::, ,:.,,.� � � (b3� • � � � � �- .o zs.!+ns .. NEAD � . • tvr�t .sssW�. � � . � � � '. c..a ` � e ( I i � I i i i 1 � I � d � L-� db Figure A-1 Microtox toxicity anaiyzer , (top view) � , I _ � . , ctl� � � � � � ■ . � � � � � � , t� d C] � t� . . . � . . . o� S�n �\ 1? \ h il Figure A-2 Sampfe preparation fQr standard Microtax test � A-2 � � r � , � . . . . . � . . � o . . . . . � . . . � . ! DATA REDUCTION AND CAI.CULATION OF AN ECSa VALUE [1] CaJculate �he controf ratio fR}. Typicatly there is some light loss caused by the passage of time during the test. 7herefore a biank or control ratio {Rt3 is calc�lated and aii numbers corrected for this naturai fight loss. R� = tt� -= Fo� Where lt� = light level {t) at incubation time (t) a# the control (e) lo� - light level t�? at incubation zero time (Oa of the control (c? I�1 �alculate the gamma (I'1 far ea+�h sample concentration. Gamma is defined as the ratio of ligh� remaining at a giuen t'rme to the amount of {ight #ost to taxic $xposure: `t = RtIQ - {t = (lo x Rt) - 1 t� It Where to = light emitted at time = 0 It = light emitted at time = t (5 or 15 minutes) !f a sample is relatively nan-toxic at a particular concentratior�, the light output lt is . not appreciably fess than the time-carrected blank, Rtlo. Based on the reietionship above, it #ollows that a sample which is relatively non-toxic yields a f. value which is relativety smafl. a relativeiy toxic sarnple, on the other hand, woufd cause lt to be smaller than R�to, an:d waufd yield a relatively targe f vaiue. [3J :Plot f versus con��ntratian on a log;{oa araph and caiculate EC50. 7he EC50 value is found by piotting gamrna versus conc�ntration an a lag-log graph and fitting the best straight line thrnugh the points. A 50°to Iight loss eorresponds ta It = 0.5 Rtlo, or, substituting into the equatian above, when f = 1 . The concentration on the plot at which (` = 1 is the ECso value. A-3 � �. ' � ' � � � APPENDIX B BIOSCIENCE MANAGEMENT, tNC. BI-1000 ELECTROLYTIC RESPlROMETER 4 ep ratinq princiale of the electro�sis c,�.li; When properly assembled, the intemal' chamber of the reactor/ cXr�e� ::=_,a�c� efectrolysis cell assembly is sealed off sV.:c� M��ocaN ElS�TRf� � 6 e: 2G�E from the atmasphere (Fig. B-1). When e��T�.�TE • , microorganisms in the reaetor vessel �I4� o���i� , metabolize substances in the test i � = =-t�-ys:s c___ EL�CTi2G�rTE � sample they cons►ame 02 ancl produce " � CO2. The CO� is absorbed in the KOH � . . . AC�PtC12 - C]2� . trap by tt�e KOH solution. The resuft is � �cSGQeE�j a net loss of gas equai to the volume ��TA��z of 02 consumed and the creation of = . � - I�� r'x.ASS FS9ER �� ��. s l i gh t v a c u u m. T h e v a cuu m causes a VI� =oTAss.� decrease in tMe electrol�rte level in the �Yo�oXto� sa.urt zoti o r ute chamber f h o t e electrol sis c II. Y e When there is approximately 1 ml ;a�E change in electroiyte {evel, contact R=ac-T� vE;s'ct� between tMe sensor eleetrode and 'I electrolyte is broken, causing the cell �li to be activated. An e(ectric current is generated and passed through the ����T"G elect�olyte between the two ' submerged electrodes. The current hydrolyzes water in the electrolyte solution. �� Figur� B-1 Bioscience Management � electrolytic respirom�ter electro�ysis cell Oxygen is produced at the positive and reactor vessel electrode accoiding to Faraday's Law: � H?O + 2 e' --> ' N2 + %s �2 , Thus 02 is added to the 'reactor vessel untiC the original pressure is- reestablished. � The hydrogen is vented to the atmosphere. When the p�essure is reestabtisF�ed the ' reaction stops and the amount of OZ generated is caiculated and stored in the , compu#er. A magnetic stir bar in the bottom of the reactor prouides mixing and faciiit�tes oxygen transfer into the sample. g_1 V . y ! ' . . �. . . . / � . � . . . . . � Z�2� O OSE',�YtOZiGYt� _ PH�NE (612)4234441 28�5•145th SVeet West,Rossmount,Minne�ota MpYQR FAX (612)4235203 Mailing Address: Edward 8.MCMenomy P.O.8ox 510,Rosemount,Minnesota 55468•05t0 COUNCILMEMBERS Sheil2 Klas&Bn �ju4.11� T�7Ot�Ce .lames(Red}Slaats �J! 1V Harry Wilicox D�nnis Wipperm3nn ZONING TEXT AMEI�tI3MENT PETITION AOM�r�4srFv,TOR Stephan Jitk TQ PERMIT COAL ASH DISPQSAL IN NONHAZARDQUS INDUSTRIAL WASTE Ct?NTAINMENT FACILITIES Petitioner: USPCi. Inc. To Whom It May Concern: NOTICE IS I3EREBY GTVEN, the �ity Council of the City of Rosemount will haid a pubiic hearing on Tuesday, June 1, 1993 in the Council Chambers of the City Hall, 2875 145th Street West, beginning at 8:00 p.m,, or as soon thereafter as possible. The purpose of the hearing is to consider an Zoning Ordinance Text Amendment that would permit the disposal of cQai ash in nonhazardous waste industrial containment facilities. Gurrentiy ihe ardinance prohibits the disposal of ash from incinerators, resaurce recovery facilities and power plants, The petitioner, USPCI, Inc.,�aperates a nonhazardaus industrial waste land disposal facility at 13425 Cflurthouse Boulevard and wishes to accegt coal ash wastes at this facility. The property is located on the south side of Courthause Bouievard (STH SS) east of US Highway S2 and north of County Road 3$ is legally described as: A tract of land lying in Sections 19, 20 and 29,Township i 15N, Ran�e 1$W, all in the City of Rosemount, Dakota Caunty, Minnesota, cornmencing at the SW eomer of the Fast 1J2 of the Southeast lf4 of said Section 19, thence east aud southeasterly along the centeriine of County Road 38 to its intersection with thc North and South Quarter Section Line of Section 24; thence north along said North and South Quarter Section Line of Section 29 and the Narth and South Quarter Section Line of Section 20 to the southwesterly right-of-way line of State Trunk Hi�hway S5; thence northwesterly along the southwesterly right-of-way line of said Highway 55 to its intersection with [he centerline o€the Chicaga and Noxthwestern Transportatian Company right-of-way, thence southwesterty alan� the centerline of said right-of-way to its intersection with the west line of the East 1/2 of the Southe�st 1/4 of Sectian 19; thence south along said west line to the point of commencement. Persons wishing to speak on this zr�ning amendment petition are invited tv attend this meetir�g an Tuesdav Tune 1 1992 at 8•Q4 o m or submit written comments prior to the hearing to the Rt�semaunt Planning Departrnent, 2$75 145th Street 'UVest, Rosemount, MIMI 55068. Dated this 4th day of May, 1993, Susan M. Walsh, Ciiy Clerk City of Rasernount Dakota Caunty, Minnesota . ��// �( �ver�l�ings �omi�.g �(Jt,�S �llosemoun�f� .. US PCI, INC. b f ` J i ZONING TEXT AMENDMENT PETITION ' ' , ' MAILING LIST ' t. Koch Refining Campany 34-01900-010-02 P.O. Box 2256 34•0)9Q0-010-Q6 �chita, KS 67201 34•0]9U0-011•t0 I' . 34•019Q0•010-62 � 34•0190Q-01 U-8U 34-02000•010•35 ' 34-02000-010-38 , 2. Chica�o & NW Trans Co 34-Ot900-010-50 t N WSTN CTR 3401900-010•82 Ghicago, It 60606 3�•02000-010-27 _ 34-02t100-D 10-75 , _ _ 3. Paul J. Nieland 34019U0�010•52 1325Q Ctaytort Avenue E Ros�mount, MN 550&8 - 4. Meiro Waste Control Commission 34•01900-010-86 Mears Park Centte : 230 f Fifth Street �� St. pau1, MN 55101 ' 5. Qrrin Kirschbaum 34-�2000•010-01 13220 Doyle Path 34•02000-010•11 Rosemnunt, MN 55Q68 6. Joseph M. & Julie A. Simones 34•02000•010-08 I 13273 Pine Bend Trail ' Rosemount. Mn 55068 ' 1. Pine Bend Developmeni Go. 34-0200Q-030 13 ' °r6 Meivin G. Astleford 34•02�Ofl•010•25 ' 1200 Highway 13 West 34-020U0-01D•28 Burnsville, MN 55337 34-02000-010•39 � 34•0200Q•Q10•$2 34•02900•Ot4-01 �� 34•029U0•O t U•20 34�0290�•011=25 34-Q2900-010•35 i : _ 34•03�00•U10-Qt _ 34-fl3000•O fi0-19 I�I _ 1- , �:- 8. USPCI, inc. 34-020�0•Q11.5Q . , ---�-' Suite 500 34•02000•D11•60 __� _{<. ---- - - ' = � - �;�, ..� 5i5 West Greens Road _ _ _ _, � '_ ,_� - ---- = � Hnuston, TX��77Q67-4524 - .�,....,,.,.._ - � - - �=' —=-= J- -- n _ _ .. . _ . ` _ -' �� �,.��,. 9. Ninth Street Prap.. Inc. _ 34•02000•0T0•31 ' One Gommerce Green 515 W Greens - Suite 5fl0 Houston, TX 77067 ' 1�. R.W. Sev�rson 34•0200t1�010•77 ' 3389 140th Street East ' Rosert�ount, Mn 5506$ ll. James H. Kromschroeder 34•D2000-Of0�86 y , , ,� � 13625 Courthoase Blvd • RR 2 , � ` Rosemount, Mn 55Q68 12 Masahiro & BrBnda Sugii 34-�20tt0-010-88 13701 Courthouse Btvd Rosemount, Mn 5506$ 13. Rich T. Surger 34•02900�010•10 M. G. Astfefard 1200 Highway 13 West Burosville, MN 55337 14. Calvin V. & Eleanar C. Twining 34•U29fl0=010-11 548a 142nd Street East Rosemount, Mn 5506$ 15. Dale B. & Betty L. Agre 34-02900•O10•15 14175 Eilers Path Rosemount, MN 55068 16. Raymond A. & Rasella Rahn 34•030U0-010-09 3855 145th Street East 34•03400�010�25 Rosemount, MN 55068 34•U30Q0-010-30 17. Marlin W. & Joann Rechtzigel 34-03QQ0•013-35 14727 Claytan Avenue fast Rosemount, MN 55068 ]8. The Salberq Construction Co. 34-03000•010-40 13245 Clayton Avenue Rvsemount, MN 55068 19. Spectro Alfoys Corp, 34-334D0-010•O1 13220 Doyle Path • Box 10 34-33400-020-q1 Rosemount, MN 55068 34-33400�030-01 34•83400-040-01 34•34Q00•04U•02 34-34000-050-02 2Q Hollenback & Nelson, ine. 34•33400•050-01 7700 Wentworth Avenue South 34•33d00•O60-D 1 Minneapolis, MN 55423 34•33400-070-01 � 34-33400•080•Q 1 22. Eagle Sanitation, Inc. 34•33400-D10-Q2 Box 228 - 34-33�00-�20•02 Newport, MN 55055 34-3340U-030•02 23. Rex Craft APPItCANT USRCI Suite 210 1445p South Robert Traii Rosemount. MN 55D68