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Home My WebLink About5.e. Koch Air Quality Monitoring Sites � - . • ��"T,�,�.� ��. � � - � �-�' -_ - 3� _ �s LAK ' �.�„�,�". � T ,;,: � , �� 31 '• � '3 '��33 75 34 � --_-_ o ,,�' +� �8 11 ; . .� , a..�.� a '`� �_ �'� � � � � �� 6 3 5 ? � 2� 1 � � 73 4 = 3�� y . a �� 70TM � � ,� �6 26 '� 1 � � � 63 7 IN V 9GR E,o � s r. uc. ,49 Z 8y� H T S�(75 R �3 2 a,N ,. ` , ia 63� �`�' _ \/ �.�— . 1�=�, 16 ` , 63 � �� 2�� 15 14 ; *� � sz ss �i 3 �e � .. -. � .. w4 . � . 2 63 (9 20 � � 73 � ze. � e',, � �' 1 � r �I P;� O . �.AA ♦ NO�' . m 3o W -E o a _ � w ,� j �R Y k� C L O D � � 2� 30 r�,� : 7� v` o� ; p � � 29 28 "27 ; _ -_ S 4 No�- ,. 1 .. . . . . �W TN T .�� NOTM tT. ( . �.. . . � • - L q °o � � 5g o s 3 3� ' �C� Z 34 'S'�. , " ,'� , f_ �, �� C� .r•�� . �r�► �r►� �►�►��►y►�► . �. �, -�.:a " '` , .' _ 1- � _ _ s��► ►s y► � � �----,�.. � r� � 'i'' ��. , . 7 ; 16 15 4� � (� 18 9� ,* 3 ' $ i • f - � . U � � ��i . � � . . . 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PHASE! o�rz�+eg AlR QUAL/TYMONITORING SYSTEM DESlGN ' Ar�vund Koch Re�ning Company - -. ;. . , > LOCATI�N ..COMPOUND : < FIELDMB EQUiPMENT SAMPE.E FREQUENCYiDURA174N DETECTIDN LINlIT,GpAL .. ,. < , <: ,;;: : ..:. ::. ; .. ; :.: .:... . :::...: ; 1,2,3,8 Fisid: Benzene, Toiuene, Xylene Photovac Gas Cfiromatograph(Field GC) Integrated 4-hour sampie, Continuai p� Lab: Benzene,Tolnene, Xylene, Fieid Canister Event canister activated during ppb Ethyibenzene,Ethylene Dibromide, (Laboratory analysis using Gas episode, with 30 minute sampie Trichioroethylene, Chloroform� ChromatographylMass Spectrometer Methylene Chioride� Vinyi Chio�ide [GClMSj) 1,2,3 Field: Suifur�ioxide{S02) Puise Fluorescence Reai Time, Continuous 5-t0 Rpb 6,7,8,10 Telemetered to MPCA 1,2,3,4 Fieid: Total Reduced Sulfur(TRS) Pulse Fiuorescence with Converter, Reai Time, Continuous 5-10 ppb 5,6�7,8,10 -or-Thermal Oxldizer Telemetered to MPCA 1,2,3,4 Lab: Particulate Matter(PM10) PM10 Sampler Time-lntegrated sampis; 24-hour PM10: 5-10,uglm•3 5,6,8,10 sample every 6 days{Every 3 days at locations 5 and 8) 1,2,3,4 Lab: Formaidehyde Absofbant Tube with High Performance Time-integrated sampie; 24-hour ppb 5,6,8,10 Liquid ChromatograpMy(HPLC), using sampie every 6 days(also activated Ultraviolet{UV)Detector during episodes) 9. Fieid: Wind Speed,Wind Direction, Meteoroiogical Station Reai Time, Continuous Wind Speed: z i mph Relative Humidity,Temperature, Telemeiered to MPCA Wind Direction: 0-� Stability, 8arometric Pressure Temperature: t 0.1°F" 2,6,8 Field: Wind Speed,Wir�d Direction, Meteorological Station Reai Time, Continuous Wind Speed:Z 1 mph Temperature, Stability Telemetered to MPCA Wind Direction: 0-540° Temperature: t 0.�°F 10$9-04-1 MONPLANI . � � � �, . :M �ES/GN � a,: ---..._ � ,,, -- °°°°e�w .. �� N �� a --- <,, 9rv t,.� �,�"� �° _ � ';, s � c,, m ,..'' � Q ' ; r,,,� O w y�w � , , �I�� ;:: ,, , . . ,' - y� �,�� _ ; , ; Q m . L E F R E Q U E I�I C Y l O U R A T I O t�f D E't E C T I Ot�#IiMITGtJAL Q'1 , . Et Er[ Qt �CQ� � .:< ' .:: ...... .: ; , � _ , W �, ,;> ad 4-hour sample, Continuai ppb 1 � c,,, ;;;; , "'_'� " �� p W ��;t�p W � i � � N � -.i � '�; - — r;z, inister activated during ppb � � � �' � � 'with 30 minute sampie� � � � n � . � ��: � � � $ • A N W . . . � � . W � 1f = �""� N .. ---'� {�j r (,�p -Y! m,a .; r � — '�.r�,� � 1� � 1 � � ' 4 r e, Continuous 5-10 ppb .� � w � �.� red to MPCA -� �� W _ .� _ � e, Continuous 5-10 pPb > " s.��s +ve. .. ISLaNp � T C' � � � w : � w � a �,co� ; � W ." red i4 MPCA z � �� .� � . � N.. _ � . . W . . . . � �° m ., � �, egrated sampie; 24-hour PM10: 5-10,ug1m�3 � � � � �.»w� .A.�� very 6 days(Every 3 days � �, ns 5 and 8) � � � � � --,,,"'-, � {� ,� � N �+tC�C�ai W � v � °' � `��,.� � �o N cn �� .1, t�grated sample; 24-hour ppb � -A ,.q, ,; � N� �, A 3very 6 days(also activated � + �cacs .� � w - _ - .,� (31SOC18S} � �,,.- _ � _ ' �,��" _: o � �`s'f �, � U' �e, Continuous Wind Speed: Z lmph - d �. � "'" ered io MPCA Wind Direction: 0-5� I t'�� 7 'a � i Temperature: t 0.t° � ��;� Q � �� Cr� � ,�,.._..- � '� �v ~ N "` m ie, Cantinuous Wind S eed: 1 � `` � P z mph } �"��`� � � ' � � � � j .-i ' � ered io MPGA Wind Direct�on: 0-540° ' � , .�.-� r" � "`i Temperature; t 0.1°F � � �` Q 1 ,�� MON��nN, � o . PHASE I/ 0��»89 ; AfR QUAL/TY MQNiTOR/NG SYS�"EM DESIGN Around Koch Refining Company ' Lt3CATiON COMPOUNQ ; 'FIELD/lAg EQUIPMENT SAMPL�.FREQUENCYlDURAT10Pf DETECTION GMtT GOA[ ,:: .. ,:, „ 11,12,14 Field: Benzene, Toluene, Xylene Photovac Gas Chromatograph(Fieid GC) lntegrated 4-haur sampie�Continual ppb Lab: Benzene, Toluene, Xylene, Fieid Canister Event canister activated during ppi� Ethyibenzene, Ethylens Dibromide, (Laboratory analysis using Gas episode�with 30 minute sample Trichioroethylene, Chforoform, Chromatography/Mass Spec#romet�r : Methylene Chioride� Vinyi Chlo�ide [GClMS)) 1,2,3,4 Lab: Benzene,Toluene, Xyiene, �eld Canister 2�t-hour sample every 6 days ppb 5,8,10,91 Ethylbenzene, Eihylene Dibrom�de, (Laboratory anaiysis using Gas (aiso activated du�ing episodes) 12,14 Trichioroethylene,Chloroform, Chromatography/Mass Spectrometer Methyle�e Chloride, Vinyi Chioride (GC/MS]) • 11,12,14 Field: Suifur Dioxide(St�2) Puise ftuorescence Real7ime, Continuous 5-1 p ppb Teiemetered io MPCA 11,12,t 4 Field: Totai Reduced SWfur(TRS) Pulse Fluorescence with Converter, Reai Time, Continuous 5-10 ppb -or-Thermai Oxidizer Telemetered to MPCA - 1,2,3,4 Lab: Aluminum Oxide, Barium, PM10 Sampier From Phase I 24-hour sample every 6 days PM10: 5-14,ugfm-3 5,6,8,10 Chromium, Yanadium, Arsenic, (every 3 days at locations 5 and 8) Nickei Metals, PAHs: Benzo(a)Pyrene Phenoi n�m,3_"�m.g 1),12,14 Lab: Particuiaie Matter(PM10), PM10 Sampier 24-hour sample every 6 days PM(10): 5-10 pgtm�3 Aluminum Oxide, Barium, Chromium, (every 3 days at Ic�ca�o�s 5 and 8) Vanadium, Arsenic,Nickel Metais, PANs: . Benzc�(a)Pyrene n�m•3-��m•� Phenoi 11,12,14 Lab: Ft�rmaidehyde Absorbant Tube with High Performance 24-hour sampie every 8 days ppb Liquid Ghromatography(HPLC), using (also activated during episodes) Ultraviolst(U� Deiector 13 Fieid: Wind Speed, Wind Direction, Meteorologicai Station Real Time, Continuous Wind Speed:z 1 mph Relative Humidity,Temperature, Telemetered to MPCA Wind Directian; 0-540° Stabiiiry, Barometric Pressure Temperature:t 0.1°F 14 Field: Wind Speed,Wind Direction, Meteorological Station Aea1 Time, Cantinuous Wind Speed:�1 mph Temperature, Stabiliry Telemetered to MPCA Wind Direction: 0-540° Temperature:t 0.1°F 1089-04-1 MONPLAN2 PHASE I+ PHASE!l ` oarZ��89 AlR QUALITYM�NITORING SYSTEM DESiGN Arourrd Koch Refining Company . >.. ;. ; LOCATI�N ;C�MPQUNQ FlEC:DIL.A�EQUIPMENT SAMPLE FREQUENCY![3URATiO�[ DETECTlON�UMtT GOAC ;: ; _ . .. <:, . ,. . <. _,; . . ;:: ; , > ,:; :. : . ; . .. 1,2.3,6 Field: Benzene� Toluene, Xylene Photovac Gas Ghromatograph (Feld GC) integrateci 4-hour sample, Cantinual p� 11,12,14 Lab: 8enzene, Tofuene, Xy�ene, Fieid Canister Event canister activaied during Ppp Ethylbenzene, Ethylene Dibromide, (l.aboratory analysis using Gas episode,with 30 minute sampie Trichloroethylene. Chloroform, Chromatography/Mass SQectrometer Methyiene Chlo�ide, Vfiyi Chloride [GC/MS�) i,2,3,4 L,ab: Benz�ne, Toluene, Xytene, Field Canister 24-haur sampie svery 6 days ppb 5,$,18 Ethyib�nz�ne, Ethylene Dibromide, (Lab��atory analysis u�ing Gas (also activated during apisodes) . 11,i 2,14 Trichloroe#hylene, Chloroform� ChromatagraphylMass Spectrorneter Methylene Chioride, Vinyi Ghloride [GC�MSj) 1,2,3,6 Field: Suifur Dioxide(SU2) Puise Fluorescence Real Time, Continuous 5-10 pRb 7,8,10 Telemetered to MPCA 11,12,14 t,2,3,4 Field: Total Reduced Sulfur(1`RS) Pulse Fluorescence with Converter, Real Time�Continuous �-�p p� 5��=�� -or-Thermai Oxidizer Teiemetered to MPCA 10,11,12,14 1,2,3,4 Lab: Particulate Matter{PM10}, PM10 Sampier 24-hour sample every 6 days PM10: 5-10,ugtm•3 5,6,8,10 Aluminum Qxide, Bafium,Chromium, (every 3 days at locations 5 and 8) �1,12,i 4 Vanadium,A�senic, Nickel Metals, PAHs: Benzo(a)Pyrene ng/m 3-»!rglm 3 Phenol i,2,3,4 L.ab: Farmaldehyde Absorbant Tube with High Performance 24-hour sample every 6 days ppb 5,5,8,10 Liquid Chromatography(HPLC), using {als�activated during episodes) i 1,12,14 Ultravioiet{UV)Detector ' 9,13 Field: Wind Speed, Wind Direction, Meteflrological Station Reai Time, Continuous Wind Spesd:z 1 mph Relative Humidity,Tem perature, Telemetered ia MPCA �nd Direction:0-540° Stabiliry, Barometric Pressure Tempefature•#0,1°F 2,6,8,14 Fieid. Wind Speed,Wind Directiony Meteorologicai Station Rea!Time, Continuous Wind Speed:z lmph Temperature, Stability Telemetered to MPCA Wind Direction: 0-540° Temperaiure: t 0.1°F 1089-04-1 � MONPlAN3 t .��.IR (�UALI�'�'MD1\T.I�'��NG SYST�1Vl � Around Koch Ref�ining Company SYSTEM MANAGEMEN�" (JRGANIZATION Oi�GA�'Y�ZA�'IONAL STR�C�'L��E � MINNES(?TA D&PARTMEN?' KOCHREFINWG OF HEALTH COMPANY E�►i�mivlogicsl StuaFy Operating D81� He.alt6 Risk Assessmenr Public Iaf+vnuatioa .DAKUTA Ct�UNT'Y v I'ublic Health Department sy�a�r��nc �y��n� � . Notificatr�Plen Management * o Area Residents � Episc�de Logs Odor Diaries MINNESOTA PDLLUTI4N OTHER AREA CONTROL AGENCY INDUSTRIES Laborstory Data #Dako� Cormty Sheritl"s D�ep�er�ieat is r�sponsible fvr receiviag aad Operabiag D:ts Moaitoring Data compiliag r�eports af an odor or emissioa iacideat fr�m Kocb Reftniag Public InRvrraa�ioa Risk Assessment Compaay and commuarcatiag t6is inlS�rmatit�to t6e apptivpriate parihies. �oas-oa-� . • ,�,r�i 27,�ees � AIR Q�T��IT�MO.��I�'aR.�N� S�'`ST.E.M Around Koch Re�g Compa.ny SYSTEM MANAGE�E1�7' �RGANI�ATI�7N F(JR .L�AK�1 TA CC�UNT�' ao�v , o� cai�rssro.x�xs BMERGENCY PLTBLIC HEALTH DIRECT�R/ sER vrcEs ENt�IRON�IENTAL HEALTH SERYICES DIRECT4R SYSTEM PROGRAM MANAGER {I.O FTE`) . , . HEALTH RISK FTELD SUPFORT CONTRAGTED A5SESSMENT TECHMCIAN SERVICES S.ERi�ICES (0.2 FTE) {I.0 FTE) (0.2 FTE) METEDROLOGY QUALIT'I' DATA PR�CIJREML�NT ODOR S3'UDY ASSURANCE ANALYSIS ASSISTANCE STUDY AUDIT �osa-Qa-� Apri12T.198a � AIR Q�I.��L.ITY MCC�.IV7TORING ��''STE� Around.�o�h Refirur�g Cvmpany S�'STEM MAI�AGEMENT ORGANIZATInN �o� �I�vN�so�� .��,uT�o�v cor�T�a� ��E�vc� � DIREClOR AIl2 QIIALI7'Y DIYISION SU�'ERVISOR PROGRAM DEVEL01'MEENI'SECTTON MOMTURtN(.i UMT QUALITY LABORATORY SUPPORT DATA FIELD � ASStTR.4NCE SERVICES SERVi'CES A.N.4LYSIS TECHMCIAN (1.0 FTE) (I.Q FTE) (O.S F`TE) � (1.0 FTE) (I.Q FTE) RISK PROCUREMENT ASSESSMENT SERV7CES (Existing) (Exiis'trag) 1089-04-1 Aprii 25.1989 ,� , , ESTIMATED CAPITAL �TS-PHASE i � INSTRUMENTATfON INSTRUMENT NUMBER COST,ea. TOTAI.COST Suifur Dioxide{S02) 6 10,000 . 60,000 Totai Reduced S�ifur(TRS} 9 i 3,000 117,000 Particulat� Matter{PM10) 8 4,000 32,000 Formatdehyde(HCHO) 8 500 d,000 MsteoroloBY(General) 3 1 Q,Q00 30,000 Meteorola9Y(SpeCiat) 1 15.000 15,000 V4C (Cannister) 4 �4,�00 16,Q00 Telemetry Equipment- Remote 10 5,000 50,000 Strip Chart Recorders 20 1,500 30,000 ' Mass Fiowmeters 2 3�000 6,Q00 S02 Calibrators{pn-Site) 6 5,Q00 30,000 Orifice Kits/Manameters t 1,500 f,500 Automatic Catibration Controilers 10 5,000 50,000 Photovac GC 4 48,000 72,000 GC/MS(H�lu/�innegan ITD) 1 1QO,C10Q 1QO,OflO Dilutian System 1 i0,000 10,000 Gas Standards 4 10,000 40,000 Vehictes 1 12,400 12,Q00 TOTAL �6�5,500 EST/MATED CAPfTAL COSTS-PHASE Il /NSTRUMENTATlQN iNSTRUMENT NUMBER C�ST,ea. TOTAL GOST Suifur Dioxide(S02) 2 1 Q,000 20,000 Total Reduced Sulfur(TRSj 3 13,000 39,000 . Particulate Matter{PMfO) 3 4,000 12,Q00 Formaidehyde(NCH4) 3 500 1,500 Meteorology(Generai) 1 1 O,UQO 10,000 Meteo�ology{Special) 1 15,OOQ 15,Q00 VQC(Gannister) 6 4,000 24,000 � Telemetry Equipment- Remote 4 5,000 20,000 � Strip Gh$rt Rscorders 10 1,500 15,000 Mass Fiowmeters 0 �,OtX3 0 S02 Calibrators(On-Site) 2 5,000 14,OOp Orifice Kits/Manometers 0 1,500 0 Automatic Calibratian Gontroilers 3 5,000 15,000 Photovac GC 3 t8,000 54,000 GGtMS (HNu/Finnegan ITD) 0 100,OQ0 0 Dilution System 0 ' 10,000 0 Gas Siandards 0 10.000 0 VehiCtes 1 12,000 12,Q00 Tt? AL �247,5Q0 TOTAL ESTiMA7ED INSTRUMENTAT/ON CQSTS: $923,00� PHASE/+PHASE l/ 1Q89-04-1 ' Od/27/89 - ESTIMATED CAPITAL C�TS—PHASE l � SiTE PREI�ARATION ._. . , ITEM NUMBER COST,ea. TOTAL C�ST Shelters 9 15,000 $135,OOQ . Power 6 1,000 6,000 Leases � 6 1,000 6,000 HVAC 6 2,500 15,000 Phone Lin�s 9 1,000 8,000 Miscellaneous 10 2,OQ0 20,OQQ TOTAL �191,Q00 ESTIMATED CAPITAC COSTS—PHASEli SITE PREFARAT/ON ITEM NUMB�R CQST, ea. TOTAI COST Shefters 3 15,000 $45,000 Power 4 1,OQ0 4,UOQ Leases 4 1,400 4,OQ0 HVAC 4 2,500 10,000 Phone Lines 3 1,000 3,000 : Misceilaneous 4 2,000 8�000 TOTAL $74�000 TDTAL EST/MATED StTE PREPARATIpN COSTS: $265,Uf10 PHASE l+PHASE ll �oss-aa-1 oai2�tas « ..,, . � � GOST SUMMARY A/R G?UALITY MQNITQRING S YSTEM ...,.., _--r---- Around Koeh Refining Company • TOTAL ESTiMATED PR ECT CC7STS PHASE l - ITEM COST TOTAL COST �- CAPITAL COSTS _.T_ _ ` ESTIMATED QPERATJNG Gf?STS-PHASE! AAiNUAL COSTS - IfiEM NUMBER CE�ST, ea. TOTAL COST Rower 10 1,000 10,00� Telephane 10 600 6,000 Spare Parts/Consumabies 10 5,Q00 SO,OQfl Transportation 1 Q 500 5,000 Lab Space 100Q 15 15,Q00 Labor 6 40,000 24Q,000 lndependent Audit 1 40,OOU 40,40Q ' Computer Data Entry,GPU Time 1 40,Q00 4Q,000 TQTAL �406,000 EST/MATEt7 ADD/TIONAL OPERATING CCISTS-PHASE l/ ANNUAL COSTS iTEM NUMBER CQST, ea. TOTAL COST Power 4 1.�0� 4,400 Telephone 4 600 2,�00 Spare Parts/Co�sumables 4 5,000 20,000 T�anspartafion 4 500 2,OOQ Lab Space p 15 � labor 0 4Q,Q00 p Independent Audit 1 10,Q00 10,�00 Computer Qata Ent . CPU Time 1 2t�,�QO 20,DUfl TQTAL �58,400 4�D� �, �oas-aa-, ,E'ja � � oar27�ss � g � `�( �/.� p �...� � ? � �c�c� . � . `� � ��,s`.�' -�d ��,j�''a c-'S-xL.�c_,� C � � � AD �3t7C Z�R I`� AIR �LITX MCkTi'1C�2I2� SYSt�'i A� � �Il�U �ANY '�A7t'r AP'RIT, �7� 1989 7;00 - 9:� p.nt. Inver Grove Beights City &�].]. - Cbuncil �rs 81Sti Sarbara Avenue, 7.nver Grcyve �eights AC�IDA 1. Review ager�a/ap�rave minutes of April 13 (enclosed) 2. Work Plan: Air �.iality I�itoring System in Pine Bend Area* ! "�,�G:�o 1�-� � �j - t•S�ni tor S i te`I;o�ca�t�r``1' `�,-i - S�nple Frequency/Duratic�n - Detecticxi Limit Goals - T)atabase t+lartagement - System Management - Estimated System Costs 3. Next Steps 4. Other 3usiness 5. Adjourn *Iaformaticjn handrouts arxl m�ateria3s will be distrii�ted at the meeting If you are cuiable to attend or have ques�ions or caa�nents, please call Danna Ar�erson (450-2614) , Dakota Ccxu►ty Public Heatth Dep�arta�nt .a , • • �E�TING MINUTES AD HOC TASK FORCE AIR QUALITY MONITOR2NG SYSTEM AROUND K�CH REFINING COMPANY April 13, 1989 Inver Grove Heiqhts City Council Chambers Meeting No. 5 �1TT�NDEE5: Members f �€ Affi�iat�on �oe Balsan�k Resident FhylTis Riesland (Alternate) Resident Jim Benson Resident Vern Krein (Alternate) Resident JoAnne E13.�r Resident Warren Kreeh City af Inver Grave Heights Bob Paliock (Alternate) City of Inver Grave Heights Kri.sty Marnin City of Eagan Jael Smith (Vice-Chair} MPCA Air Quality Division Gary Eckhardt (Alternate) MPCA Air Quality Division Donna Anderson (Chair) Dakata County Health Dept. George Kinney (Alternate) Dakota County Health Degt. ATT�N�1 EES: Other am AffiTiatior� Marian Krein Resident Alyce Benson Resident Richard Wedlund MPGA A�.r Quality Div�.sion Chuck Michael Malcolm Pirnie Mike Harboza Malcolm Pirnie Pat Thompson Kach Refining' Company Ronald Larson Pine Hend Landfill Melissa Young News I1 Bob Timm News 11 1. CAL,� TO QRDER Donna Anderson called the meeting tc� Qrder at 7;06 p.m. Additions �o ,P�aenda: 1. Donna Anderson requested the addition of twv items to the agenda: o An announcement of the status of the Feasibility Study for an epidemiological study in the vicinity of the Koch Refinery, 1089-04-3 " � Meeting Minutes - Ad Hoc Task Force 4/13/89 • � ' Page 2 • o A discussion of hydrocarbon monitoring, to be presented by Mike Barboza of Malcolm Pirnie. Without objection, these items were added to the agenda. $�,�t�.c�rns/Co rections to M}�nutes of Mareh 30 1959: None Motion to approve the minutes of the March 30, 1989 meeting as written: Motion by Balsanek, Second by Benson. Unanimous. 2. A�OUNCEMF;NT REGARDING FEASIBILITY STUDY FOR EPIDENIIQLOGICAL STUDY Donna AndersQn relayed an announcement by Dak4ta County Commission�r Steve Loeding that as of this morning (April, 13, 1989) , Dakota County and Koch Refininq Company have reached an agreement whereby Koch Refining Cc,mpany will fund a study designed to determine the feasibility of conducting an ' spidemialogical study in the vieinity of the Koch refinery. The epidemialagical study, if determined to be feasible, would determine whether the emissions in the area surrounding Koch refinery either cause asthma or adversely affect asthmatic children livinq in the refinery area. Donna Anderson indicated that the funds for the feasibility study, the cost of which has yet to be determined, wauld be provided directly to Dakata County by Koch Refining Company. Donna stated that the feasibility study would be conducted by a aonsultant selected by Dakota County from a list of qualified organizations agreed upon between the County and Iioch. The feasibility study would include an exhaustive literature search, a revi�ew af Koch emissions, and a review of other epidemiologieal studies similar in nature. Dakota Count}� would be responsible for final decisians regarding all aspects of this study. If warranted after completion of the literature review, the feasibflity study would lay out the actual study design, protocols, and estimated cost. Additionally, a peer review panel would be conv�ned to review the work of the seleeted consultant: Donna indicated that Dakota County is prepared to expedits the feasibility study immediately. Commentslt„�y�stions: o Jim Bensan; Jim asked whether Kaeh has committed ta fund bath the feasibi].ity study . and the larger epidemiologi�al study. Answer (Donna Andersonj : Kach has agread to fund only the feasibility study. Funding sources for the epidemiologica], study have yet to ba determined. 3089-Q4-1 , Meeting Minutes�Ad Hoc Task Force 4/13 f 89 • Page 3 o Bob Pollock: Bob asked what role the MDH will have in the study. Answer {�onna Anderson) : Donr�a indicated that Dakota County wiil manage the feasibility study, �nd that MDH data from the earlier asthma study will be made avaiiable to the i.nvestigators. o Jae Balsanek; Joe asked what the limit of the funding agreement for the feasibility study was, Answer (Donna Andersonj : Donna replied that there was no limit stated in the agreement. o Jim Benson; Jim asked what the anticipated time frame was for the feasibility 5tudy. Answer (Donna Anderson) : Donna replied that the MDH had previously estimated approximately 7 months for the feasibility study. 3 , �SCUSSION• TC?�& H�DRQCARBON MON�TORING Chuck Miehael intraduced the discussion of total hydrocarbon monitoring by indicating there were technical concern� in cantinuing ta include ambient total hydrocarbom m�nitoring as an ele�nent of the manitoring plan. As the Task Force had earlisr agreed to include total hydrocarban manitoring in the system, Chuck expiained that it was appropriate to diseuss the deletion af total hydrocarbon monitoring with the Task Force priar to removing it from the system design. Mike Barboza summarized the technical concerns, shared by the MPCA Air Quality Division and Malcolm Pirnie, by e�cplafning that ambient measurement of total hydrocarbons results in a gross measurement, in ppm, rather than measurement of specific hydroearbans in the ppb range, Further, Mike explained that measuring for total hydr�carbons was not as useful as measuring for other compounds, although it eould be used as a trigger during episodes. Following a general discussion af the advantages and disadvantages of total hydrocarbon monitoring, it was agreed by the Task Force to delet� total hydrocarbon monitoring from the system design. 4. �FELIMINARY SYSTEM DESIGN A, Monitor Site Locations Chuck Miehael provided a handout of the locations of the monitoring sites, numbered 1-13, and briefly reviewed the loeations og the monitars with respect to the Koch refinery and the surraa�ding topography. Site numbers 1-10 were ex�lained a� the same as those previously presented, with site numbers 11-I3 as additional sites in the vicinity of the Ashland refinery. Additionally, site number 14 was 10$9-04-1 , _ . Meeting Minutes �Ad Hoc Task Force 4j13/89 . Page 4 identified as the control site to be located outside the influence of the two refineries and does not presently aPP�ar on the handout. B. Sample Freguency/Duration and Detection Limit Goals i Chuck Michael provided three handouts entitled: . o "Phase I Preliminary Air Quality Monitoring System Araund Koeh Refining Company, " dated 4/12/89 (Draft} o "Phase II Preliminary Air Quality Monitoring System Around Koch Refining Company, " dated 4/12/89 (Draft) o "Phase I + Phase II Preiiminary Air Quality Monitoring System Around Koch Refining Company, " dated 4/12/89 (Draftj Chuck Michael explained that the Phase S handout swnuaarized the compounds to be mQnitored durinq Phase I and the locations where eaGh compound wiil be monitored, including metearolagical data; the field equipment required for eaeh lc�cation and the corresponding lab �quipment that will be required; the sample frequency and duration for each , compound, including telemetry arrangements for those parameters monitored continuously; and the detection limit qoals anticipated for each respective parameter. Chuck Michael then explained that, even though the eonceptual design agreed to earlier by the Task Force had included ben2ene in Phase I and additional VOCs in Phase II,' it was recommended that all proposed VOCs be moved to Phase I. The reasoning was that a field GC is required for ' benzene analysis in the field during Phase I anyway, and as long as the field GC was acquired in Phase I, the full suite of VQC analys�s might just as we11 be run during Phase I � rather than waiting fQr Phase II as no significant additicnal equipment wouid be required. Chuck Michael explained that at some locations there would be field equipment capable of sampling VOCs and formaldehyde during epis4des, such as an event eanister or a�sorbant tube. Moving to the Phase II handout, Chuck Michael explained tt�e additionai compounds that would be monitored during Phase II, includir�g metals and PAHs at the identified 3aeatians installed during Phase I. Additional monitoring . sites would also be added, specificaily at locations 11, 12, and i4 (Sxte 13 is an existing MPCA monitor site near the Ashland refinery that would be exganded to include meteoarological capabilities during Phase II) . 1089-04-1 , , Meeting Minutes �Ad Hoc Task Force 4f 13/89 • Page 5 The Phase i + Phase II handout was explained as the sumnzary of all locations and a].i manitored compounds, . representing the complete ambient air c�uality monitoring . �ystem design as fully implemented. �omme�,ts/Ques�ion,�s o Joe Balsanek; Joe asked for a definition of "episode". Answer; The definition of ar� "episode" is currentiy somewhat subjective, and an appropriate threshold of odor and/or discomfort will be developed prior to implementation of the system. o Joe Balsanek: Joe questioned whether, given a definition of an "episrade" or "event", the samp�.ers couid be activated remotely. Answer: The event samplers can be designed to be activated remotely, typicaily through a dial-up telephone signal using an authorization code. a Warren Krechs Warren abserved that only two af the six meteorolagical sfiations were equipped to monitor relative humidity and barometric pr�ssure. Warren suggested that the monitaring system may be less than complete if this infarmation is not a�quired at all meteorological sites. Additionally, Warren suggested a loss of opportunity in data collection from the wind speed indicators if the indicators are only capable af datecting wind speeds greater than or equal to 2 mph. Answer: The meteoralogieal questions will be referred to Jahn Wilsafl, who will meet to discuss these questions with Warren prior to the next meeting. o Joel Smith; Joel commented that the system as designed < was an extensive monitoring program requiring significant resources, and that the data obtained would indeed be helpful in defini;ng the ambient air quality in the vicinity around Koch refinery. Joel indicated that it may be necessary to establish priorities bas�d on the final cost estimates for the system. 5. �ESENTATION: CONC�FPTS OF OUALITY ASSURANCEIOUALITY GONTROL PROCEDURES Richard Wedlund provided a presentation regarding Quality Assurance/Quality Cantrol (QA/�C) procedures for air programs, and explained th� meaning and importance af QAfQC elements such as; accuracy, preeision, comgleteness, representativeness, traceability, independent sources for QA audifis, control limits, and detection limits. Richard stressed that indegendent personnel should always be used fQr QA audits and review. 1Q89-04-1 . , Meeting Minutes �d Hoc Task Force 4/13/89 � Page 6 Richard Wedlund briefly diseusseci tl�e QA/QC difficulties experienc�d dur�.ng the OHCNPS program, in partieular the VOC sample�s collected 3,n Tsnax tubes. 6. �YSTEM AN.p�3A�.�BASE MAN f;EMEN� : Donna Anderson requested that the Task Foree assist in the development of system and database management procedures by identifying the characteristics and options that would be desired by the Task Force. Comme�s/Suggest�.ons: o Jim Benson: Jim suggested that Dakota County and MPCA ' function as co-manaqers of the monitorinq system, and that they be authorized to select third party assistance. Jim suggested that the third party should not be the managers af the s�rstem. o Bob Pollack: Bob suggested th�t the County operate the system, the MPCA provide QA/QC audits; and that an outside laboratory perform the analysis. o Joe Baisanek: Joe questioned k�ow many laboratories wouTd have the capabilities to perform these extensive analyses. Answer (Gary Eckhardt) : Gary explained that anly about 2 labs in the metro area currently have the capabilities to do ai.r analysis. The MPCA has the lenowledge and experience, but additional iaboratory equipment would need to be acquired. o Kristy Marnin: Kristy asked whether the MPCA and the County could manage the system, if the funding was avaiiable. Answer (Gary Eckhardt) : The MPCA would need an additional GC/MS in order ta perform the analysis; a cast of approximately Si0Q,000. o Joe Balsanek: Joe asked who perfanaed the data interpretatian once the samples are analyzed. Answer (Gary Eckhardt) : The interpretatian would be performed by those performing the sample analysis. Metion to recommend that Dakata County and MPeA operate and manage the air guality monitoring system, with outside assistance as may be neeaea; however management of the system may not be delegated. Motion by Benson, Second by Marnin. Discussion: o County and MPCA can determine lead agency be�ween themselves. 1089-04--1 � • M�eting Minutes�Ad Hoc Task Force 4/13/89 � Page 7 o Bob Pollock: Bob suggested amending the mation to read that Dakota County and MPCA will provide the Task Force with a specific operations plan. (Agreed by Benson, aqreed by Marnin) ; Mo�ion amended. o Warren Krech: Warren stated that, in the end, the County should be respansible as it is a County issue concerning Caunty residents, and therefare the County -- should be the primary system manager. Call for the Questian: Joe Balsanek. Vote: Unanimous. 7• �ASK,�'�RCE �ESPONSE T4 KOCI�'�TATFMEN� OF „�ARCH 30 Donna Andersan suggested that the response by the Task Foree to Koch Refining Company�s concerns contained in their statement of March 30 is now complete in that adequate definitfon of the scope of the monitoring system design, parametezs, goals and - ob�ectives, have been fuily developed. Additionally, the scope for the inv�stigation of the feasibility af performing an epidemiolc�gical study has beer� determined. With this definition of scope it is the hope that the ambient air monitoring system can proceed as can the feasibility of performing the egidemiologieal study. Foliowing a brief discussion, the Task Force eoncurred that the elements of concern noted in Koch's statement of March 30 have been substantially addressed, and confirmed that the Work Plan, containing final system design elements, would be completed by the Task Force in accordanee with the ariginal schedule established as the end of April, 1989. 8 . NEXT MEETiNG The next meeti.ng of the Ad Hoc Task Force shall be Apri1 27, 1989 beginning at ?;�0 p.m. at the Inver Grove Heights eity Council ehaatbers. 9. �DJOtTRN Motion to adjourn: Mation by Benson, Second by Marnin. Unanimous. Meeting adjourned at 8s32 p.m, �.asg-a�-� DRAFT PHASE/ ; o4f,vas PRFtIM/NARYA/R QUALITYMQNITORING SYSTEJI/1 DESIGN Around Koch Refining Company ' LOCATION COMPOUND ' FIELD/LAB EQUIPMENT SAMPLE FREQUENCY/DURATI�N DETECTION LIM1T GOAI t,2,3,6 Field: Be��ene Photovac Gas Chromatograpfi(Field GC) Integrated 4-hour sample,Continuous ppb Lab: Benzene Field Ganister Event canister activated during ppb {Laboratory analysis using Gas episode, with 30 minute sampie Chromatography/Mass Spectrometer [GC/MSJ) 1,2,3 Fie1d: Suifur Oioxide{S02) Puise Fiuorescer�ce Real Time,Coniinuous 5-1 p ppb 6,7,8,10 Telemetered to MPCA 1,2,3,4 fisld: Tatat Aeduced Sultur(TflS) Puise Fiuorescence with Converter, Reai Time, Continuous 5-10 ppb 5,6,7,8,10 -or-Thermal Oxidizer Telemetered to MPCA 1.2,3,4 Lab: Pariiculate Matter(PM10) PM10 Sampler Time-integ�ated sampie; 24-hour PM14: 5-10 uglm•3 5.6,8,10 sampie every 6 days(Every 3 days at locations 5 and 8) 1,2,3,4 Lab: Formaldehyde Abso�bant Tube with High Performance Time-integrated sample; 24-hour ppb 5,&,8,10 Liquid Chromatography(HPIC), using sampie every 6 days(also activated Ultravioiet(UV)�etector during episodes) 9 Fieid: Wind Speed, Wind Direciion, Meteoroiogicai Station Real Time, Continuous Wintl Speed:z 2mph Relaiive Humidity,Temperaiure, Telemetered to MPCA Wind Direction: 0-540° � . Stability,Barometric Pressu�e S#abiliry: 95-20° Temparature: t 0.1°� 2,6,8 Fietd: iNind Spsed, 1Aiind Oirectlo�, Meteorologicai Station Rea1 Time, Continuous Wind Speed: z 2mph Temperature, Stabifity Telemetered to MPCA Wind Direction: 0-540° Stability: 15-20° Temperature: t 0.1°F to8s-oa-� MONPLAN t C7RAFT PHASE fl . �+�#y8� PRELIM/NARYA/R QUALlTYM4NlTOR1NG SYSTEM DESIGN . Around Koch Re�ning Company LOCATION COMPOUND , FIELO/LAB,EQUIPMENT SAMPLE FREQUENCYiDURATION DETECTiON L!M!T Gt'�AL _ : 1,2,3,6 Field: Toluene, Xylene Fieid GG From Phase t Integrated 4-hour sample,C�ntinuous ,ppb i.ab: Toluene, Xylene, Field Canister Event canister activated during ppb Ethylbenzene, Eihytene Dibromide, (Laboratory analysis using Gas episode, with 30 minute sampis Trichioroeihylene, Chioroforrn� Chromatography/Mass Spectrometer Mathylane Chlo�ide. Vin 1 Chlaride GG/MS ) 1 t,t 2,14 Field: Benzene.Toluene, Xyisne Photovac Gas Chromatc�graph(Fieid GC) integrated 4-hour sampla,Continuous ppb �ab: Benzene. 1'oluene, Xylene. Field Canister Event canistsr activated during ppb Ethylbenzerte, Etfiylene�ibromide, (Labaratoty analysis using Gas episode, with 30 mi�uts sample � Trichloroethyiene, Chloroform, Ghromatography/Mass Spectrometer Meth IenQ Chioride, Vinyi Chloride GCIMS]j 1,2,3,4 Lab: Benzene, Toiuene,Xylsne� Field Canister 24-hour sample every 6 days ppb 5,8,10,1 t Ethylbsnzene. Ethytene Dibromide, (Laboratory an�lysis usi�g Gas (aiso activate�during episodes) 12,14 Trichloroethylene, Chloroform, ChromatographylMass Spectrometer Meth ene Chloride, Vinyl Chloride GC/MS]) 11,12,14 Field: Sulfur Dioxide(S02) Pulse Fiuorescence Reai Time, Continuous 5-10 ppb Telemetered to MPCA t y,12,14 Field: Total Reduced Suifur(TRS) Pulse Fluoresc�nce with Converter, Reai Time, Continuous 5-10 ppb -or-Thermal Oxidizer Telemetered to MPCA 1,2,3,4 L�b: Aluminum (3xide, 8arium, PM10 Sampler Fram Phase I 24-hour sample every 6 days PM10: 5-10,uglm•3 5,6,8,t 0 Chromium, Vanadiurn, Arsenic, (every 3 days at locations 5 and 8) Nickei Metals,PAHs; 8enzo{a)Pyrene n9/m'3-•�91rr►•3 ' Phenol 11,12,14 Lab: Particulate Matter(PM10j, , PM10 Sampler 24-hour sampie every 6 days PM(10): 5-1a Nglrn.3 Aluminum Qxide, Barium, Chromium, (ev�ry 3 days at locations 5 and 8) . Vanadium, Arsenic, Nickei Metals, PAHs: Benzo(a)Pyrsne n9�m•3-»N9�m•3 Phenoi t i,t 2,14 Lab: Formaidehyde Absorbant Tube with High Performance 24-hour sample every&days ppb Liquid Chromatography{HPLC). using �aiso activafed during episodes) Ultravioiet{UV)Oetector i 3,t 4 �eid: Wind Speed, wi�d Direction, Meteorologicai Station Reat Time, Cantinuous Wind�peed: a 2mph Relative Humidity, Temperature, Telemetered to MPCA Wind Direction; 0-540� Stability, Baromeiric Pressu�e Stability: 15-20� tp8g_ a-� Temperature: t 0.t°F M N LA 2 DRAFT PHASE I+ PHASE 1/ o�,�ti89 PRELiMlNARY'AlR QUALITYMt�NITORING SYSTEM DESIGN � Around Koch fiefining Company � , . L;�CATION C�MPOUND ' FIELDJLAB EQUIPMENT : , SAMPLE FAEQUENCY/DURATION DETECTION LIMiT GOAI. 1,2,3,6 Field: Benzene, Toluene, Xylene Photovac Gas Chromatograph(Fieid GC) Mtegrated 4-hour sample, Continuous ppb 11,12,14 lab: 8enzene, Toluene,Xylene� Field Canister Event canister aetivated during ppb Ethyibenzene, Ethylene�ibromide, (�aboratory analysis using Gas episode.with 30 minute sarnpie Tricfilorpethylene, Chioroform, Chromatography/Mass Spectrometer MeiMytene Chioride, Vinyl Chioride [GCJMS]j t.2,3,4 Lab:8enzene.Tofuene. Xyiene. Field Canister 24-hr�ur sampie every fi days ppb 5,8,10 Ethylbe�zene, Ethylene Dibromide, (Labo�atory analysis using Gas (also activated during episodes) 11,12,14 Trichlo�oethylene,Chloroform, Chromatography/Mass Spectrometer Methylerts Chioride, Vi�yl Chioride (GC/MS�) ___ t,2.3,6 Fiefd: Sulfur Dloxide(S02) Puise Fluorescence Fieai Time, Continuous 5 10 ppb 7,8,10 Telemetered to MPCA 11,12,14 1,2,3,4 Fieid: Total Reduced Sulfur(TAS) Puise Fiuo�escence with Converter, Rea!Time, Continuous 5-10 ppb 5,6,7,8 -or-Thermai Oxidizer Telemetered to MPCA 1d,11,i2,14 1,2,3,4 Lab: Particulate Matter(PM10), PM10 Sampier 24-hour sampie every 8 days PM10: 5-1�Ngtm•3 S,fi,8,t 0 Aluminum Oxide, Barium, Chromium, (every 3 days at locations 5 and S) 11,12,14 Vanadium, Arsenic, Nickel Metais, PAHs: , 8enzo{a)Pyrene ��m.3_„�m.� Phenoi � 1,2,3,4 Lab: Formafidehyde Absorbant Tube with High Performance 24-hour sarnple every 6 days ppb 5,6,8,10 Uquid Chromatography{HPLC), using (also activated during�pisodes) 11,12,14 Uitraviolet(UV) Detectar 9,i 3 Fieid: Wind Speed, Wind Direciion, Meteorological Statio� Real Time, Co�tinuous Wind Speed:z 2mph Aelative Humidity,Temperaiure� Telemetered to MPCA Wind Direction: 0-540° 5tability, Barometric Pressure Stabiliry: 15-2U° Temperature: t 0.1°f 2,6,8,t4 Fieid: Wind Speed. Wind Direciion, Meteorological Station Real Time, Continuous 1Nind Speed: �2mph Tempe�ature, Stability Telemetered to MPCA 148�3-44-1 MONPLAN3